Influence of electrode material on the electrochemical behavior of the absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide

2021;
: 53-59
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University
5
Lviv Polytechnic National University

The electrochemical behavior of carbonate solutions of the quinhydrone at different concentrations 1, 5, 10, 20, and 30 g/dm3 at the exposure time 0…12 days on different electrode materials - Ni and Au were studied by the cyclic voltammetry (CV) method. The catalytic properties of gold different from nickel in the anodic oxidation reactions of the quinhydrone catalyst are noted.

1. Mokhatab, S., Poe, W. A., Mak, J. Y. (2019). Sulfur Recovery and Handling. Handbook of Natural Gas Transmission and Processing, 271-305. https://doi.org/ 10.1016/b978-0-12-815817-3.00008-3
https://doi.org/10.1016/B978-0-12-815817-3.00008-3
2. Slyuzar, A. V., Znak, Z. O., Kalymon, Ya. A., Bukliv, R. L. (2019). Metody ochyshhennja i pereroblennja sirkovoden'vmisnyh gaziv (ogljad) [Methods of purification and processing of hydrogen sulfide-containing gases (review)].. Voprosy Khimi i Khimicheskoi Tekhnologii - Issues of Chemistry and Chemical Technology, 3, 83-97. DOI: 10.32434/ 0321-4095-2019-124-3-83-97 (in Ukrainian).
3. Slyuzar, A., Znak, Z., Kalymon, Y., Helesh, A. (2020). Study of Oxygen Chemisorption During Regeneration of Quinhydrone Absorbing Solution in the Apparatus with a Continuous Bubbling Layer. Chemistry and Chemical Technology, 14 (2), 257-263. https://doi.org/ 10.23939/chcht14.02.257
https://doi.org/10.23939/chcht14.02.257
4. Yavorskyi, V. T., Slyuzar, A. V., Kalymon, Ya. A., Mertsalo, I. P., Tryhuba, O. O. (2006). Elektroliz vidpratsovanoho pohlynalnoho rozchynu khinhidronnoho metodu ochyshchennia haziv vid sirkovodniu. [Electrolysis of the spent absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide]. Voprosy Khimii i Khimicheskoi Tekhnologii - Issues of Chemistry and Chemical Technology, 6, 99-101 (in Ukrainian).
5. Kalymon, Ya. A., Yavorskyi, V. T., Chaiko, N. I., Znak, Z. O. (2001). Pohlynalni rozchyny na osnovi khinhidronu dlia ochyshchennia haziv vid sirkovodniu. [Absorbing solutions based on quinhydrone for gases purification from hydrogen sulfide]. Visnyk NTU - Bulletin of NTU "Kharkiv Polytechnic Institute", 18, 145-150. (in Ukrainian).
6. Znak, Z. O., Yavorskyi, V. T., Lievashova, V. L. (1990). Protsess polimerizacii quinhydronea v shchelochnoj srede. [The process of quinhydrone polymerization in an alkaline environment]. Kinetics and catalysis, 31(1), 197-202. (in Russian).
7. Slyuzar, A. V., Khomyak, S. V., Kalymon, Ya. A. (2019). The influence of exposure time on changing of the properties of the soda solution of quinhydrone during the quinhydrone catalyst preparation. Chemistry, Technology and Application of Substances, 2(2), 68-72. https://doi.org/ 10.23939/ctas2019.02.068.
https://doi.org/10.23939/ctas2019.02.068
8. Yavorskiy, V. T., Kalymon, Ya. A., Znak, Z. O., Chajko, N. Y. (2000). Tehnologija prygotuvannja poglynalnogo rozchynu na osnovi quinhydroneu dlja ochyshhennja gaziv vid sirkovodnju [The technology of preparation of absorbent solution based on quinhydrone for gases purification from hydrogen sulfide]. Ekotehnology and resource-saving, 5, 56-59. (in Ukrainian).
9. Yavorskyi, V. T., Slyuzar, A. V., Kalymon, Ya. A., Mertsalo, I. P. (2005). Elektrokhimichni vlastyvosti khinhidronu v luzhnomu rozchyni. [Electrochemical properties of quinhydrone in alkaline solution]. [Electrochemical properties of quinhydrone in alkaline solution]. Visnyk NTU - Bulletin of NTU "Kharkiv Polytechnic Institute", 16, 166-169. (in Ukrainian)
10. Mazanko, A. F., Kamar'yan, A. F., Romashin, O. P. (1989). Promyshlennyj membrannyj elektroliz [Industrial membrane electrolysis]. Moskva: Himiya. (in Russian).
11. Barsukov, V. Z. (Ed.), Borysenko, Yu. V., Buket, O. I., & Khomenko, V. G. (2016). Promising Materials and Processes in Technical Electrochemistry. monograph. Kyiv: KNUTD.https://www.researchgate.net/ publication/331821560.
https://doi.org/10.30857/8902
12. Pokhmurskii, V. I., & Khoma, M. S. (2008). Koroziinavtomametaliv ta splaviv.[Corrosion fatigue of metals and alloys]. Lviv: SPOLOM. (in Ukrainian).
13. Slyuzar, A. V., Kalymon, Ya. A. (2020). Vplyv komponentiv na okysno-vidnovni vlastyvosti khinhidronnoho pohlynalnoho rozchynu [Influence of components on the redox properties of quinhydrone absorption solution]. Voprosy Khimii i Khimicheskoi Tekhnologii - Issues of Chemistry and Chemical Technology, 5 (132), 88-97. http://dx.doi.org/10.32434/0321-405-2020-132-5-88-97
14. Guin, P. S., Das, S., Mandal, P. C. (2011) Electrochemical Reduction of Quinones in Different Media: A Review. International Journal of Electrochemistry, 2011, 1-22. DOI:10.4061/2011/816202
https://doi.org/10.4061/2011/816202
15. Gouws, S., Barton, B., Loyson, P. L. R., Zeelie, B. (2008). Electrochemical production of alkoxy-substituted phenols. Electrochimica Acta, 53(13), 4544-4549. DOI:10.1016/j.electacta. 2008.01.047
https://doi.org/10.1016/j.electacta.2008.01.047
16. Rafiee M., Nematollahi D. (2007). Voltammetry of Electroinactive Species Using Quinone/Hydroquinone Redox: A Known Redox System Viewed in a New Perspective. Electroanalysis, 19(13), 1382-1386. DOI: 10.1002/elan.200703864.
https://doi.org/10.1002/elan.200703864
17. Astudillo, L. R., Rivera, L., Brito-Gómez, R., Tremont, R. J. (2010). Еlectrochemical study of 1,4-benzoquinone on gold surface modified. Journal of Electroanalytical Chemistry, 640(1-2), 56-60.https://doi.org/ 10.1016/j.jelechem.2010.01.005
https://doi.org/10.1016/j.jelechem.2010.01.005
18. Chaudhari, V. R., Bhat, M. A., Ingole, P. P., Haram, S. K. (2009). Self electro-catalysis of hydroquinone on gold electrode in aqueous un-buffered media. Electrochemistry Communications, 11(5), 994-996. DOI: 10.1016/j.elecom.2009.02.046.
https://doi.org/10.1016/j.elecom.2009.02.046
19. Fang, F. L., Win, W. X., Dong, G. M., Tian, G. Y. (2007). Cobalt hydroxide film deposited on glassy carbon electrode for electrocatalitic oxidation of hydroquinone. Electrochimica Acta, 52(11), 3654-3659. https://doi.org/ 10.1016/j.electacta.2006.10.027
https://doi.org/10.1016/j.electacta.2006.10.027
20. Danylov F. Y., Protsenko V. S. (2016). Liniina ta tsyklichnavoltamperometriia. Knyga 1. [Linear and cyclic voltammetry. Book. 1]. Dnipro: Lira. (in Ukrainian).