Macroinitiators on the basis of new peroxide surface active monomers

Authors: 
Ananiy Kohut, Roman Fleychuk, Orest. Hevus and Stanislav Voronov

The surface active properties of new peroxide maleic monomers were investigated. The regularities of their copolymerization with styrene were studied. Peroxide polymers containing ditertiary alkyl peroxide groups in side substituents of backbone as the prospective high-temperature free radical macroinitiators were synthesized.

[1] Voronov S., Tokarev V., Oduola K., et.al.: J. Appl. Polym. Sci., 2000, 76, 1217.
[2] Voronov S., Tokarev V., Datsyuk V., et.al.: J. Appl. Polym. Sci., 2000, 76, 1228.
[3] Guyot A. and Tauer K.: Adv. Polym. Sci., 1994, 111, 43.
[4] Capek I.: Adv. Colloid Interface Sci., 2000, 88, 295.
[5] Busfield W. K., Jenkins I. D. and Heiland K.: Eur. Polym. J., 1994, 30, 1259.
[6] Guillaume J. L., Pichot C. and Guillot J.: J. Polym. Sci., Part A: Polym. Chem., 1990, 28, 137.
[7] Fleychuk R.I., Hevus O.I. and Voronov S.A.: Russ. J. Org. Chem., 2003, 39 (12), 1799.
[8] Kohut A.M., Fleychuk R.I., Hevus O.I. and Voronov S.A.: 11th Internarional Conference on Chemistry of Organic and Elementorganic Peroxides, 2003, 238.
[9] Siggia S. and Hanna J.G.: Quantitative Organic Analysis via Functional Groups. New York, J. Wiley & Sons, 1979.
[10] Alfrey T., Bohrer J. J. and Mark H.: Copolymerization. New York, J. Wiley & Sons, 1952.