The effect of the kind, concentration and introduction method of polymeric modifiers (polyvinyl alcohol and polyvinylpyrrolidone), as well as the kind of metal chloride on the physico-chemical regularities of the obtaining process of modified metal-containing polymer-silicate materials, their morphology and properties has been examined. Using instrumental methods of investigations it was established that obtaining of metal-containing polymer-silicate materials was accompanied by intermolecular interactions between active silicate groups and functional groups of a polymeric modifier. The effect of metal-containing polymer-silicate materials on the regularities of curing and properties of polyester composites has been studied.
[1] Bykov E. and Dehtyarev V.: Plast. Massy, 2006, 1, 32.
[2] García M.: Polymer – Inorganic Nanocomposites, Influence of Colloidal Silica. Thesis Univ. of Twente, Enschede 2004.
[3] Ray S. and Okamoto M.: Prog. Polym. Sci., 2003, 28, 1539.
[4] Lipatov Yu.: Physico-Khimicheskie Osnovy Napolnennykh Polimerov. Khimiya, Moskva 1991.
[5] Billingham J., Breen C. and Yarwood J.: Spectr. Lett., 1997, 14, 19.
[6] Mittal V.: Polymer Nanocomposites: Advances in Filler Surface Modification Technique, Nova Science Publ., Weinheim 2009.
[7] Levytskyi V., Kochubei V. and Gancho A.: Chem. Chem. Techn., 2013, 7, 169.
[8] Tenkayala S., Subha M., Gorla V. et al.: J. Appl. Polym. Sci., 2010, 117, 3533.
[9] Levy R. and Francis C.: J. Colloid. Interf. Sci., 1975, 50, 442.
[10] Gancho А., Masyuk А. and Levytskyi V.: Visnyk Nats. Univ. “Lvivska polytehnika”, 2011, 700, 418.
[11] Masyuk A. and Levytskyi V.: Eastern-Eur. J. Enterprise Techn., 2014, 72, 29.
[12] Samoliuk D. and Levytskyi V.: Khim. Prom. Ukrainy, 2015, 129, 36.
[13] Pot Y.: Poliestery i Alkidnye Smoly. Paint Media, Moskva 2009.
[14] Ogur E.: Smith. Rapra Techn., 2005, 16, 12.
[15] Pluisnina I.: Infrakrasnye Spektry Mineralov. Izd-vo Moskov. Univ., Moskva 1977.