RP-HPLC with Detection by Means of ESI-MS and UV for Identification of Chromatographic Peaks of Some Hydroxy Derivatives of Epoxy Resin

2016;
: pp. 141 – 149
Authors: 

Ostap Ivashkiv, Pavel Kubica, Igor Poluyuzhin, Jacek Namiesnik, Olena Shyshchak and Michael Bratychak

Ostap Ivashkiv-1, Pavel Kubica-2, Igor Poluyuzhin-1, Jacek Namiesnik-2, Olena Shyshchak-1 and Michael Bratychak-1

  1. Lviv Polytechnic National University, 12, S. Bandera St., 79013 Lviv, Ukraine; mbratych@polynet.lviv.ua
  2. Gdansk University of Technology, 11/12 G. Narutowicza St., 80233 Gdansk, Poland

The composition of products synthesized on the basis of ED-24 epoxy resin has been studied using reversed phase high-performance liquid chromatography followed by electrospray ionization mass spectrometry (RP-HPLC/ESI-MS). The synthesized products contain free hydroxy groups and such groups, as epoxy, peroxy, carboxy or acrylate.

[1] Pasch H. and Trathnigg B.: Multidimensional HPLC of Polymers. Springer-Verlag, Berlin Heidelberg 2013.
[2] Adrian J., Braun D., Rode K. and Pasch H.: Angew. Makromol. Chem., 1999, 267, 73.
[3] Adrian J., Braun D. and Pasch H.: Angew. Makromol.Chem., 1999, 267, 82.
[4] Simal G., Paz A., Lopez M. et al.: Chromatographia, 1992, 34, 67.
[5] del Olmo M., Gonzalez-Casado A., Navas N. and Vilchez J.: Anal. Chimica Acta, 1997, 346, 87.
[6] Dark W., Conrad E., and Crossman Jr.: J. Chromatogr. A, 1974, 91, 247.
[7] van der Maeden F., Biemond M. and Janssen P.: J. Chromatogr. A, 1978, 149, 539.
[8] Twitchell J., Walker J. and Maynard J.: J. Chromatogr. Sci., 1979, 17, 259.
[9] Noel D., Cole K. and Hechler J.-J.: J. Chromatogr.,
[10] Crathorne B., Palmer C. and Stanley J.: J. Chromatogr., 1986, 360, 266.
[11] Hagnauer G. and Setton I.: J. Liq. Chromatogr., 1978, 1, 55.
[12] Shiono S., Karino I., Ishimura A. and Enomoto J.: J. Chromatogr., 1980, 193, 243.
[13] Julka S., Cortes H., Harfmann R. et al.: Anal. Chem., 2009, 81, 4271.
[14] Nordt S., Pasch H. and Radke W.: Mycrosyst. Technol., 2010, 16, 1347.
[15] Tanzer W., Reinhardt S. and Fedtke M.: Polymer, 1993, 34, 3520.
[16] Ivashkiv O., Namiesnik J., Astakhova O. et al.: Chem. Chem. Technol., 2015, 9, 313.
[17] Shunmakers P.: Optimizatsia Selectivnosti v Chromatografii. Mir, Moskva 1989.
[18] Ivashkiv O., Bruzdziak P., Shyshchak O. et al.: Chem. Chem. Technol., 2015, 9, 411.
[19]
[20] http://www.chem.agilent.com/en-US/products-services/Instruments-Systems/...
[21] https://www.agilent.com/en-us/products/liquid-chromatography/lc-columns/...
[22] Holcapek M., Jirasko R. and Lisa M.: J. Chromatogr. A, 2010, 1217, 3908.
[23] Lebedev A.: Mass-Spectrometria v Organicheskoi Khimii. Binom, Moskva 2003.
[24] Raks V. and Esaulenko A.: Suchasna Chromatografia na Hrebeni Hvyli Progresu. Avanpost, Kyiv 2014.
[25] Garcia A. and Catterton A.:1,4-Butandiol (BD) – Forensic Profile- 04-08-2004 Southeast Laboratory Miami Florida P. 02-12.
[26] Snyder L. and Dolan J.: J. Chromatogr. A, 2013, 1302, 45.
[27] Snyder L., Kirkland J. and Dolan J.: Introduction to Modern Liquid Chromatography, 3rd edn. John Wiley & Sons, Inc. NJ 2010.