Thermodynamic Studies of Bromphenol Blue Removal from Water Using Solvent Sublation

https://doi.org/10.23939/chcht10.04.515
Received: November 11, 2015
Revised: November 27, 2015
Accepted: May 12, 2016
Authors: 

Tetiana Obushenko, Natalia Tolstopalova, Olga Kulesha and Igor Astrelin

National Technical University “Kyiv Polytechnic Institute” 37, Peremogy Ave., 03056 Kyiv, Ukraine; rektif-32m@ukr.net

The investigation of thermodynamic peculiarities of bromphenol blue (BB) elimination from aqueous solutions using solvent sublation technique has been carried out. Thermodynamic properties of acid dye (BB) interaction with cationic surfactant cetylpyridinium chloride (CPC), applying Kharash method and HyperСube HyperСhem Professional software were studied. It was proven that dye-surfactant ion complex formation is a spontaneous process and does not require any external forces for its run.

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