1. JCCT
  2. All Volumes and Issues
  3. Volume 14, Number 4, 2020
  4. Properties of the Composites Made of Glauconite and Polyaniline in Aqueous Solutions of Phosphoric Acid

Properties of the Composites Made of Glauconite and Polyaniline in Aqueous Solutions of Phosphoric Acid

JCCT.
2020;
Volume 14, Number 4
: pp. 487 - 495
https://doi.org/10.23939/chcht14.04.487
Authors:
  1. Solomiia Nesterivska
  2. Victoriia Makogon
  3. Мykhaylo Yatsyshyn
  4. Ivan Saldan
  5. Oleksandr Reshetnyak
  6. Nestor German
  7. Yurii Stadnyk
1
Ivan Franko National University of Lviv
2
Ivan Franko National University of Lviv
3
Ivan Franko National University of Lviv
4
Lviv Polytechnic National University
5
Ivan Franko National University of Lviv
6
Ivan Franko National University of Lviv
7
Ivan Franko National University of Lviv

The glauconite-polyaniline composites were prepared through oxidation of aniline using ammonium peroxodisulfate in aqueous solutions of phosphoric acid on the surface of a glauconite powder. Intermolecular interaction between amorphous polyaniline macromolecules and interphase coupling of polyaniline to the glauconite surface was confirmed by X-ray diffraction and FT-IR spectroscopy. Higher concentration of phosphoric acid led to a stronger intermolecular and interphase connection because of H-bonding, and that resulted in higher electric conductivity while a magnetic susceptibility of the composites was not affected. Thermal analysis for the prepared composites confirmed the interfacial interaction between the polyaniline macromolecules and the surface of powdered glauconite.

glauconite-polyaniline composite
structure
electric conductivity
magnetic susceptibility
thermal stability
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