The Evaluation of bis(4-Methylphenylsulfonyldithiocarbimato)zincate (II) (ZNIBU) Activity in the Vulcanization of NBR Compounds and its Effect on their Mechanical Properties

Authors: 

Iara de Oliveira, Leandro Cunha, Leila Visconte, Marcelo Oliveira and Mayura Rubinger

The effect of accelerator type on the vulcanization process and mechanical properties of nitrile rubber (NBR) compounds was investigated. Three commercial accelerators were selected, N-N-t-butyl-2-benzothiazole sulfenamide (TBBS), tetramethylthiuram disulfide (TMTD) and bis(dimethyldithiocarbamato)zinc (II) (ZDMC) and compared with the compound bis(4 methylphenylsulfonyldithiocarbimato)zincate (II) (ZNIBU). Surprisingly, it was found that the optimum vulcanization time for ZNIBU showed better results than for TBBS.

[1] Ono D., Bragdon J. and Jaeger D.: Physicochem. & Eng. Aspects, 2007, 308, 141.  
[2] Nicola C., Ngoune J. et al.: Inorg. Chimica Acta, 2007, 360, 2935.
[3] Shaheen F., Badshah A., Gielen M. et al.: J. Organometallic Chem., 2007, 692, 3019.
[4] Yin H., Zhai J., Sun Y. and Wang D.: Polyhedron, 2008, 27, 663.
[5] Travnicek Z., Pastorek R. and Slovak V.: ibid, 411.
[6] Ondrusova D., Jona E. and Simon P.: J. Thermal Anal. & Calorimetry, 2002, 67, 147.
[7] Hofmann W.: Rubber Technology Handbook. Hanser, New York 1989.
[8] Mariano R., Oliveira M., Rubinger M. and Visconte L.: Eur. Polym. J., 2007, 43, 4706.
[9] Shiny P. and Rani J.: J. Elastom. & Plastics, 2006, 38, 199.
[10] Perpetuo G. et al.: Polyhedron, 2003, 22, 3355.
[11] Hamed G. and Rattanasom N.: Rub. Chem. Techn., 2002, 75, 323.