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  3. Volume 5, Number 2, 2011
  4. Functionalization of Isobutylene Oligomers and 1,2-Polybutadiene with Methyldiazoacetate in the Presence of Cu(OAc)2-2,4-Lut-ZnCl2 Catalytic System

Functionalization of Isobutylene Oligomers and 1,2-Polybutadiene with Methyldiazoacetate in the Presence of Cu(OAc)2-2,4-Lut-ZnCl2 Catalytic System

JCCT.
2011;
Volume 5, Number 2
Authors: 

Rimma Sultanova, Raisa Biglova, Tagir Yangirov, Vladimir Dokichev and Gennady Zaikov

A catalytic method of the chemical modification of isobutylene oligomers and syndiotactic 1,2-polybutadiene on the C=C bond via the [1+2] cycloaddition of metoxycarbonylcarbene in the presence of Cu(OAc)2-2,4-Lut-ZnCl2 is proposed.

chemical modification of polymers
methyldiazoacetate
metal complex catalysis

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