The polymerization ability of methylmethacrylate (MMA) dymethylforamide (DMF) solutions in the process of their radical thermoinitiated homopolymerization in the presence of intraionic dyes was investigated by a dilatometry method. It was shown that dyes can initiate the polymerization process in the presence of stardart initiator AIBN or without it. This is considerable for colored polymethylmethacrylate (PMMA) obtaining.
[1] Slominsky Yu., Popov S. and Tolmachev A.: Dokl. Acad. Nauk SSSR, 1987, Ser. B, No. 3, 50.
[2] Kulinich A. and Ishchenko A.: Uspekhi Khimii, 2009, 78, 151.
[3] Mchedlov-Petrossyan N., Klochkov V., Andrievsky G. and Ishchenko A.: Chem. Phys. Lett., 2001, 341, 237.
[4] Reichardt Ch.: Solvents and Solvent Effects in Organic Chemistry. WILEY-VCH Verlag GmbH & Co. Weinheim 2003.
[5] Matsuoka M. (Ed.): Infrared Absorbing Dyes. Plenum Press, New York and London 1990.
[6] Ulrich G., Ziessel R. and Harriman A.: Chem. Int. Ed., 2008, 47, 1184.
[7] Ischenko A.: Pure and Appl. Chem., 2008, 80, 1525.
[8] Ishchenko A. and Grabchuk G.: Theor. Exp. Chem., 2009, 45, 143.
[9] Srinivas K., Prabhakar Ch., Lavanya Devi C. et al.: J. Phys. Chem. A., 2007, 111, 3378.