diffusion

The results of analytical researches of migration processes and turbulent diffusion of exhaust  aerosols, produced by traffic flows within reserve technical lanes of highways are given. It is concluded that rotors, determined as some areas of the rotary motion of an aerosol, are always formed within the diffusion divergence field of turbulent flows of exhaust aerosol.

This paper is devoted to the method of extraction unit calculation of periodical action for direct flow and return flow of extraction processes based on an analysis of the kinetics of extraction of components of the porous structures of minerals and seeds plant material under a constant driving force. Запропонована методика розрахунку прямотечійного та протитечійного екстракторів безперервної дії на основі аналізу кінетики екстрагування цільових компонентів з пористих структур мінеральної сировини та насіння рослинної сировини в умовах постійної рушійної сили. 

Досліджено вплив довжини світлової хвилі на швидкість поглинання вуглекис-
лого газу мікроводоростями. Описано механізм транспорту вуглекислого газу із повітря
у внутрішнє середовище клітини мікроводорості. На основі математичної моделі
приросту мікроводоростей визначено коефіцієнт приросту. Отримано аналітичну залеж-
ність коефіцієнта приросту мікроводоростів від довжини світлової хвилі. Встановлено
оптимальні довжини світлових хвиль для проектування технологічних схем

In this paper the processes of admixture convective diffusion in two-phase structures with periodically located thin channels are investigated with taking into account a natural decay of migrating substance. With the help of application of appropriate integral transforms separately in the contacting domains, a solution of the contact initial boundary value problem of convective diffusion of decaying substance is obtained. The correlations between these integral transforms are found using the non-ideal contact conditions imposed for the concentration function.

The process mechanism for sorption of strontium and cesium from liquid radioactive waste using modified bentonites from Yaziv sulfur deposit was investigated. The technique for predicting the intensity of the sorption process based on the comparison of experimental and calculated values of mass transfer coefficients was proposed. It was detected that the process of sorption extraction of strontium and cesium from liquid medium using modified clay minerals may be best described by a three-parameter model of the adsorption isotherms.

In this research a number of important scientific and applied problems associated with the development of information technology for simulation based on physical analogies for objects of tourism industry and information and communication infrastructure are solved. The processes of integration of these technologies n an appropriate information system modeling for the study and construction of effective tourism and information and commu¬nication systems.

An information model of the city educational environment have been described, the processes of educational qualification growth of the individual from the birth up to full profession readiness and further increment of the knowledge potential have been analyzed. There have been suggested processes of the knowledge potential propagation within socio-communicative environment in the form of the diffusion-like model.

A series of catalysts with the deactivated external surface on the basis of HZSM-5 have been prepared by extracting aluminium atoms from zeolite crystals or by covering this zeolite surface by the products of tetraethoxysilane thermal destruction. The external surface deactivation has been found to be not the main factor of increasing the para-selectivity in the reaction of toluene to benzene and p-xylene disproportionation: decreasing the diffusion of o- and p-xylene from the catalyst pores on the external surface of zeolite crystals seems to be as the determinant.

Dependence of acrylate macroradicals concentration in polymeric matrix of 1,6-hexanediol diacrylate on time within temperature range of 45-80С has been investigated by means of ESR-spectroscopy. It has been established that experimental data do not linearize in coordinates of equation of the second order reaction, what coordinates with bimolecular mechanism of macroradicals decay. It has been suggested, that the effect of decreasing of the rate constant of bimolecular macroradicals decay in time is related with their propagation in chain propagation reaction.