The influence of Ni-containing polymer-silicate filler on the technological properties of polypropylene is presented. It was found that the introduction of silicate fillers modified by polyvinyl alcohol change the flow patterns of polypropylene melts, in particular viscosity increases and anomalous viscosity shifts. The change of thermomechanical curves of polypropylene under the action of modified silicate fillers is shown.
Viscoelastic properties of amine-cured epoxytitania composites were investigated. The composites were synthesized by the sol-gel method and analysis of their physico-mechanical properties indicated that higher TiO2 content causes the decrease in glass transition temperature of the composites. Non-linear change of crosslink density with a filler content was observed.
The ability of polymers and composites on their basis to be processed in the viscous fluid state, the choice of rational methods and technological parameters of the processes of processing are largely determined by their technological properties.
The paper describes some approaches for thermal analysis of nano-composites by finite element method.
In this paper for calculation of reinforced concrete columns strengthened with carbon laminate with suggestions based on the method of calculation according to the recommendations NIISK and Sika on the basis of deformation model calculation according to regulations . To determine the additional eccentricity introduced by bending flexibility factor, which is derived using in Eurocode 2. The algorithm for calculating strengthened at the primary level loading columns.
The essential effect of the nature and the content of the fine-grained modified polyvinylpyrrolidone magnesium hydrosilicate on the degree of crystallinity and crystallite sizes of polypropylene was established. This effect is caused by the change in the structural formations at the phases interface and by the nature of intermolecular interactions. Fine-grained particles of the modified magnesium hydrosilicate act as the additional centers of crystallization within the polymer composite material.
A novel conductive ink, suitable for employment in a pressure-sensitive automatic system, was prepared and characterized via scanning electron microscopy, FTIR and differential scanning calorimetry. The ink was obtained as a composite by mixing a solution of ethyl acrylate-methyl acrylate (50/50 ratio) copolymer and carbon black and graphite into a solvent standard for acrylic polymers. The ink average electrical resistance ranges from 40 ohms/cm to 150 ohms/cm.
In this work the electrical properties of vapor detectors, formed from composites of conductive carbon-black and insulating organic multifunctional polymers having metal ions complexing ability, were investigated. The new composites are tailored to produce increased sensitivity toward specific classes of analyte vapors. Resonant frequency shift of a Quartz Crystal Microbalance (QCM) and dc resistance measurements have been also performed simultaneously on polymer-carbon black composite materials.
Preparation and properties of composites consisting of two continuous interpenetrating phases, at least one of them is the polymer phase, are presented. Three different kinds of such composites are discussed: polymer-polymer (PVC-PMMA), polymer-mineral (PMMA-gypsum) and polymer-metal (PVC-Wood alloy). Composites were prepared by filling the porous matrix made of one component with other component in the liquid state which was then solidified by polymerization (PMMA) or cooling (Wood alloy). The obtained composites were characterized mainly by mechanical testing, e.g.
The influence of the nature and amount of the nanosized polyvinylpyrrolidone silicate modifier obtained as a result of the combined sol-gel transition on the supramolecular structure, as well as physical, mechanical and thermo-physical properties of polycaproamide has been determined. The modifier has proved to significantly increase the degree of crystallinity of polymer, and thus tensile strength at break, surface hardness and thermal resistance of a composite.