The research works dedicated to the formation regularities of solid fuels chemical structure were analyzed. Modern conceptions of coals chemical structure, which are becoming deeper owing to tooling growth and facts accumulation, were examined by means of critical comparison of different hypothetical models of solid fuels “molecular” structure. The most general points of the respective theories were formulated, according to which “soft” influence on coal structure primary elements bonds system allows bringing its chemical potential to the maximum.
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