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  3. Volume 10, Number 4, 2016
  4. Oxidation of Unsaturated Aldehydes by Organic Peracids

Oxidation of Unsaturated Aldehydes by Organic Peracids

JCCT.
2016;
Volume 10, Number 4
: pp. 401 – 411
https://doi.org/10.23939/chcht10.04.401
Received: May 15, 2016
Revised: July 05, 2016
Accepted: September 11, 2016
Authors: 

Zorian Pikh, Roman Nebesnyi, Volodymyr Ivasiv, Andrij Pich and Sofia Vynnytska

Zorian Pikh-1, Roman Nebesnyi-1, Volodymyr Ivasiv-1, Andrij Pich-2 and Sofia Vynnytska-1

  1. Lviv Polytechnic National University, 12 S. Bandery St., 79013 Lviv, Ukraine; pikh@polynet.lviv.ua
  2. Institute of Technical and Macromolecular Chemistry, RWTH Aachen University and Leibniz Institute for Interactive Materials, e.V. Aachen, Germany

The paper is dedicated to studies of kinetic regularities of oxidation of unsaturated aldehydes by organic peracids. The routes of products formation were considered, kinetic model of the oxidation reaction was designed and reaction activation parameters were calculated based on experimental data. New data on reactivity of aldehydes with various structures in the reaction with peracids were obtained.

oxidation with peracids
unsaturated aldehydes
mechanism of the reaction
kinetic and activation parameters.

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