Regularities of the reaction of oleic acid with a mixture of ethanolamines have been investigated under non-stationary conditions in the presence of H-form of cation-exchange resin KU-2-8 as a catalyst. The effect of a ratio between reagents and the catalyst on the acid conversion, selectivity and products yield has been determined. N-acylation of mono- and diethanolamines by an oleic acid was found to be more intensive compared with esterification of hydroxy groups of ethanolamine.
[1] Pletnev M. (Ed): Poverhnostno-Aktivnye Veschestva i Kompozitsii. Spravochnik, OOO «Firma Klavel», Moskva 2002.
[2] Pop G., Bodachivskyi Yu., Donets O.: Naftohazova Haluz Ukrainy, 2014, 5, 32.
[3] Akram M., Zaman W., Salman Z. et al.: J. Sci. Res., 2010, 41, 31.
[4] Mithun G. Mondal, Amit Prabhakar Pratap: J. Oleo Sci., 2016, 65, 663. https://doi.org/10.5650/jos.ess15276
https://doi.org/10.5650/jos.ess15276
[5] Protsyshyn V., Holik M.: Katalyz i Neftekhymyia, 2007, 15, 108.
[6] Liu K., Nau A., Shaw J.-F.: J. Agric. Food Chem., 2001, 49, 5761. https://doi.org/10.1021/jf0107858
https://doi.org/10.1021/jf0107858
[7] Chebaksarov A., Khudoleeva E., Besogonov M.: Pat. RU 436767, Publ. Dec. 20, 2011.
[8] Melnyk S., Reutskyy V.: Chem. Chem. Technol., 2014, 8, 93.
[9] Mitchell D., Smit D.: Akvametriya. Khimiya, Moskva 1980.
[10] Ogorodnikov S. K.: Azeotropnyie Smesi. Khimiya, Leningrad 1971.
[11] Abdul Aziz H., Kheireddine Aroua M., Yusoff R. et al.: J. Surfact Deterg., 2016, 19, 11. https://doi.org/10.1007/s11743-015-1736-0
https://doi.org/10.1007/s11743-015-1736-0