Grape Pomace Extract as Green Vapor Phase Corrosion Inhibitor

2018;
: pp. 410-418
1
National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”
2
National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”
3
Department of Inorganic Substances and Ecology, Ukrainian State University of Chemical Technology
4
National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”
5
National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”

The inhibition effect of the grape pomace extract during the early stage of steel corrosion under adsorbed thin electrolyte layers was investigated. The present study was carried out to identify the components present in the 2-propanol grape pomace extract by GC-MS analysis. Gravimetric, electrochemical impedance spectroscopy, potentiodynamic polarization, scanning electron microscopy, and FTIR techniques were used to study the corrosion inhibitive. Polarization measurements have indicated that these green inhibitors acted through mixed type inhibition. SEM studies have evidenced the formation of a protective film over metal surface while FTIR supported by molecular modelling has proved that this shielding effect was caused by aldehydes particularly 2-phenylacetaldehyde and 3,7-dimethylocta-2,6-dienal.

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