Basicity and Nucleophilicity Effect in Charge Transfer of AlH3-Base Adducts: Theoretical Approach
This study permits to explore the interactions involved in Lewis acid $\left(\mathrm{AlH}_3\right)$ and Lewis bases: $\mathrm{CO} ; \mathrm{H}_2\mathrm{O} ; \mathrm{NH}_3 ; \mathrm{PH}_3 ; \mathrm{PCl}_3 ; \mathrm{H}_2 \mathrm{S} ; \mathrm{CN}^{-} ; \mathrm{OH}^{-} ; \mathrm{O}_2^{-2} ; \mathrm{F}^{-} ; \mathrm{N}\left(\mathrm{CH}_3\right)_3 ; \mathrm{N}_2 ; \mathrm{N}_2 \mathrm{H}_4 ; \mathrm{N}_2 \mathrm{H}_2 ; \mathrm{C}_5 \mathrm{H}_5 \mathrm{N} ; \mathrm{C}_6 \mathrm{H}_{5^{-}}\mathrm{N}\mathrm{H}_2$.