thermodynamic parameters

Corrosion Inhibition Efficiency, Experimental and Quantum Chemical Studies of Neutral Red Dye for Carbon Steel in Perchloric Acidic Media

The Neutral Red (NR) has been investigated as a corrosion inhibitor for carbon steel (C-steel) in 1M perchloric acid using a weight loss method and theoretical calculations based on density functional theory (DFT). The obtained results revealed that NR is an effective inhibitor and its inhibition efficiency increases with the increasing concentration to attain 89.50 % at 5•10-3 M at 293 K. The thermodynamic parameters as enthalpy, entropy and Gibbs free energy for both dissolution and adsorption processes are calculated and discussed.

Adsorption of Zinc Ions in Water on Natural and Treated Clay

Adsorption of zinc ions in water on natural and treated clay has been studied. Natural clay before and after activation was characterized using TGА/DTА techniques and chemical analysis.The effects of various parameters, such as an initial concentration, temperature, pH, contact time and adsorbent concentration, has been examined. It was shown that treated clay is a good adsorbent compared to natural clay for removing Zn2+ ions and can be used instead of expensive adsorbents.