nickel(II)

Copper(II) and Nickel(II) with N,N’-bis(salicylidene)thiosemicarbazide Heterometal Complex Compounds

New heterometal coordination compounds of copper(II), nickel(II), and alkaline-earth metals with N,N’-bis(salicylidene)thiosemicarbazide have been synthesized. Using elemental analysis, IR-spectroscopy, molecular conductivity, magneto-chemical, and thermogravimetric investigations the composition and structure of the complexes of the general formula Е[МL']2∙xН2О (М2+ = Cu, Ni; E2+ = Ca, Sr, Ba; х = 1–4; Н3L' = N,N’-bis(salicylidene)thiosemicarbazide) have been examined. It has been shown that the synthesized compounds have semi-conducting properties.