New surface-active oligomers were synthesized with the alternative placement of hydrophilic and lipophilic blocks based on substituted peroxide-containing oxetanes and polyesters of higher dicarboxylic acids and polyethylene glycols of different molecular weights. By acylation of peroxide-containing oxetane with dichloroanhydride decane and dodecanedioic acids, the corresponding bis (peroxyalkyloxetane) esters were synthesized. The interaction of the obtained diesters with polyethylene glycols PEG-300 and PEG-600 led to synthesys of amphiphilic oligomers, with reactive peroxide groups in the lateral branches of the macro-chain.
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