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  3. Volume 5, Number 2
  4. Regularities of epoxide formation during the activation of Mo2B in the reaction of B-ethylalyl-a-ethyl acrylate with ter-butyl hydroperoxide

Regularities of epoxide formation during the activation of Mo2B in the reaction of B-ethylalyl-a-ethyl acrylate with ter-butyl hydroperoxide

CTAS.
2022;
Volume 5, Number 2
: 1-4
https://doi.org/10.23939/ctas2022.02.001
Authors:
  1. Zoryana Komarenska
  2. Lilianna Oliynyk
  3. Oksana Makota
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University

The regularities of epoxide formation during the activation of the Mo2B catalyst in the reaction of β- ethylalyl-a-ethyl acrylate interaction with tert-butyl hydroperoxide have been studied. The change in the composition of the Mo2B catalyst surface and its amount in the reaction mixture was studied. As well as reaction products (tert-butyl alcohol and 2,3-epoxy-2-ethylpropylethyl acrylate). It is shown that the selectivity of epoxy formation is not constant. It was found that the hydroperoxide on the non-activated form of the catalyst is consumed unproductively, and on the activated completely spent on epoxidation.

oxidation; epoxidation; kinetic regularities; catalyst; β-ethylalyl--ethyl acrylate
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