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  4. Еxperimental determination of thermodynamic parameters of 3-(5-phenyl-1-(furan-2-ylmethyl)-1h-pyrrol-2-yl)propanoic acid

Еxperimental determination of thermodynamic parameters of 3-(5-phenyl-1-(furan-2-ylmethyl)-1h-pyrrol-2-yl)propanoic acid

CTAS.
2025;
Volume 8, Number 1
Authors:
  1. D.S. Shevchenko
  2. Yuri Horak
  3. N.І. Tischenko
  4. Mykola Obushak
  5. I. B. Sobechko
1
National University Lviv Polytechnic
2
Ivan Franko National University of Lviv
3
Frantsevich Institute for Problems of Materials Science NASU
4
Ivan Franko National University of Lviv
5
Lviv Polytechnic National University

The fundamental thermochemical quantities of 3-(5-phenyl-1-(furan-2-ylmethyl)-1H-pyrrol-2-yl)propanoic acid have been experimentally determined for the first time. Using the combustion calorimetry method and the differential thermal analysis method, the combustion energy, melting point, and heat of phase transitions were determined. Standard enthalpies of combustion, formation in the condensed state, fusion and vaporisation were calculated on the basis of experimental data. Applying the two methods, the enthalpies of sublimation were recalculated to 298.15 K and the enthalpies of formation in the gaseous state were evaluated. The possibilities of applying the analytical calculation of the enthalpy of formation using the Joback, Domalski and semi-empirical methods of quantum chemical calculation are shown.

enthalpy of combustion; enthalpy of formation; enthalpy of vaporisation; enthalpy of fusion; enthalpy of sublimation; analytical calculations; pyrrole derivatives; N-substituted 3-(5-phenylpyrrol-2-yl)propanoic acids

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