dopant

Organic Synthesis and Characterization of Electrically Conducting Poly(o-Toluidine) Doped with Organic Acid

Poly(o-toluidine) doped with acrylic acid and without it was synthesized by using chemical oxidative polymerization technique. With the help of this method the polymer, poly(o-toluidine) was synthesized in the form of emeraldine salt. The oxidizing agent used for this method is the ammonium persulphate .The polymer products were characterized by UV-Visible and FTIR spectroscopy. The polymer, poly(o-toluidine) doped with acrylic acid was highly soluble in common organic solvents like m-cresol, NMP, DMF etc.

Studies on the Effect of Doping Agent on the Structure of Polyaniline

Polyaniline (PANI) doped with hydrochloric acid (HCl), sulpharic acid (H2SO4) and formic acid (HCOOH) was synthesized by a chemical oxidative polymerization technique. The oxidizing agent used for this method is potassium dichromate. The polymer products were characterized by FTIR and UV-visible spectroscopy. The FTIR results showed that the doping degree of PANI-HCOOH is the greatest one. A successful doping of HCOOH in PANI was observed in UV-visible spectroscopy. Three steps decomposition observed from the thermo gravimetric analysis (TGA).