blend

The changes in the crystal structure of polyhydroxybutyrate, polylactide, and their blends during biodegradation under the influence of bacteria and fungi were studied using X-ray diffraction analysis. It was found that microorganisms induce structural transformations in polymers, which occur without significant mass loss of the samples. X-ray diffraction analysis revealed that biodegradation is a complex multifactorial process that depends on the nature of the polymer and microorganisms and is characterized by microstructural changes in the film samples. 

The structure of extruded films based on blends of polyvinyl alcohol and poly(3-hydroxybutyrate) (PHB) was studied for various compositions. The methods of DSC and X-ray analysis were used. As the phase-sensitive characteristics of the composite films, diffusion and water vapor permeability were also investigated. In addition, the tensile modulus and relative elongation-at-break were measured. Changes in the glass transition temperature of the blends and constant melting points of the components show their partial compatibility in intercrystallite regions.