Structural Organization of Polymer Metal Complexes with Water or Phenanthroline and their Influence on Luminescence Properties
A monomer – 2-methyl-5-phenylpentene-1-dione-3,5, its solvent metal complex Eu(III)-water, hybrid metal complex Eu(III)-phenanthroline, new metallopolymers based on them are obtained. The results of above studies have shown that the configuration of the chelate unit is unchanged during polymerization. Using the electron microscopy the homogeneity of metal distribution in the polymer matrix of synthesized metallopolymer was confirmed.