rate constant

Studied of co-gasification of heavy coal tars with lignite and walnut shell in the temperature ranged from  400 to 500 °С, the flow rate of oxidand (air) ranged from 0,0005 to  0,004 m3/min.  It is established that the weigth loss of the sample mixtures in the gasification process has a S-shaped. Mathematical and graphical dependences of the influence of oxidant flow rate on the values of reaction rate constants and activation energy of gasification of experimental mixtures were developed.

The kinetic investigations of phase formation processes in the mixture which contains BaO, Al2O3, Fe2O3  were carried out. The degree of conversion and the activation energy were calculated, the dependence of the reaction rate and the rate constant on reaction temperature was determined.

Kinetic peculiarities of the early stages of the processes of acid-catalyzed hydrolysis and condensation in sol-gel systems tetraethoxysilane (TEOS)–ethanol–water have been investigated by gas chromatography. Kinetic parameters of the process, evaluated using quantum-chemical calculations, satisfactorilly coincide with the ones determined experimentally.