Peculiarities of Peroxide-Containing Reactive Copolymers Synthesis
This work deals with the study of radical copolymerization of higher esters of (meth)acrylic acid with peroxide monomer, 5-tert-butylperoxy-5-methyl-2-hexene-3-yne showing the properties of a weak inhibitor. Due to the mentioned and other features of investigated process, the composition of obtained copolymer cannot be adequately described with known Mayo-Lewis and Scaits equations. The analysis of kinetic data has allowed to propose differential equation of copolymer composition for investigated systems. A technique of quasi-stationary concentrations was not used during its derivation.