The paper presents the results of studies of the temperature dependences of the resistivity ρ(T) and the Seebeck coefficient S(T) of binary structurally disordered alloys of the Ni1-xPx system. It was found that at 0.10 < x 0.18. The resistivity ρ increases with x, the temperature coefficient of electrical resistance α decreases and becomes negative, and S also increases and becomes positive near x=0.18. These results agree with the Mooij correlation and the r-S correlation for the studied samples, namely for samples with high resistivity S> 0 and for samples with low resistivity - S <0, which is observed in some non-magnetic structurally disordered alloys. Thus, the Ni1-xPx system covers the range and behavior of electrokinetic characteristics that are characteristic of a few structurally disordered alloys. For x <0.175 dependencies r(T) and S(T) of the studied samples are similar to those observed in ferromagnetic structurally disordered iron-based alloys.
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