Structure and properties of polycaproamide composites with modified fillers

2025;
: 132-137
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University
5
Lviv Polytechnic National University

The influence of the nature of polyvinylpyrrolidone silicate fillers on the structure and properties of polyamide-6 has been established. It has been found that the introduction of polyvinylpyrrolidone silicate filler into polyamide leads to a significant increase in the degree of its crystallinity, while a change in the size of crystallites is also observed. The introduction of a filler based on co-precipitated sodium liquid glass and polyvinylpyrrolidone into polyamide-6 reduces the value of volumetric technological shrinkage and equilibrium water absorption. The change in the structure of polyamide under the influence of the filler and its modifier also affects the value of the surface hardness of composites and the Vicat softening point. 

1. Sahoo, N. G., Rana, S., Cho, J. W., Li, L., Chan, S. H. (2010). Nanocomposites derived from polymers and inorganic nanoparticles. Materials, 3(6), 3654–3731. https://doi.org/10.3390/ma3063654

2. Huang, L., Wang, Z., Xu, Y., Sun, L. (2023). Enhancing Mechanical Properties of Nanocomposites Reinforced by Electrospun PA-6 Nanofibers. Polymers, 15(3), 673. https://doi.org/10.3390/polym15030673

3. Hassan, M., Fauzi, F. (2015). A review on graphene/PA6 composites: recent advances and applications. RSC Advances, 5(84), 68456–68480. https://doi.org/10.1039/C5RA09312K

4. Kargarzadeh, H., Ahmad, I., Abdullah, I. et al. (2015). Mechanical and morphological properties of PA6 composites reinforced with cellulose nanofibers. Cellulose, 22, 2903–2912. https://doi.org/10.1007/s10570-015-0723-y

5. Al-Mulla, A., Sivakumar, D. (2021). Experimental investigations on mechanical properties and strengthening mechanisms of PA6/zeolite nanocomposites. Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications. https://doi.org/10.1177/09544062211005798

6. Randhawa, K.S., Patel, A. (2021). Influence of water absorption on mechanical properties and glass transition temperatures of polyamide6/hexagonal boron nitride composites. International Journal of Structural Integrity, 12(5), 743–759. https://doi.org/10.1108/IJSI-05-2021-0049

7. Shen, L., Du, Q., Wang, H., Zhong, W., Yang, Y. (2004). In situ polymerization and characterization of polyamide‐6/silica nanocomposites derived from water glass. Polymer International, 53(8), 1153–1160. https://doi.org/10.1002/pi.1520

8. Levytskyi, V., Masyuk, A., Katruk, D., Kuzioła, R., Bratychak Jr., M., Chopyk, N., Khromyak U. (2020) Influence of Polymer-Silicate Nucleator on the Structure and Properties of Polyamide 6. Chemistry&Chemikal Technology, 14 (4),  496-503. https://doi.org/10.23939/chcht14.04.496

9. Levytskyi, V.Ye., Masyuk, A.S., Suberlyak, O.V. (2017) Preparation and properties of polymer-silicate composites based on hydrophilic polymers. Voprosy Khimii i Khimicheskoi Tekhnologii, 6, 68-74.

10. Levyts’kyi, V.E., Masyuk, A.S., Samoilyuk, D.S., Bilyi, L.M., Humenets’kyi, T.V. (2016) Morphology and Properties of Polymer–Silicate Composites. Materials Science, 52 (1), 17-24.

11. Masyuk, A.S., Katruk, D.S., Levytskyi, V.Ye., Boiko, M.V., Kulish, B.I. (2020) Influence of metal-containing polymer-silicate filler on the technological properties of polypropylene. Chemistry, Technology and Application of Substances, 3 (1), 214-219.

12. Levyts’kyi, V.E., Masyuk, А.S., Bialopiotrowicz, Т., Bilyi, L.М., Humenets’kyi, T.V. (2018) Morphology and Properties of Thermoplastic Composites with Modified Silicate Fillers. Materials Science, 54 (1), 48-54.

13. Analiza rentgenowskich krzywych dyfrakcyjnych polimerów za pomocą programu komputerowego WAXSFIT / Rabiej, M., Rabiej, S. — Bielsko-Biała – Warszawa, 2006. — 133 p.