ENVIRONMENTAL IMPACT AND FLOWS OF WASTE BATTERIES IN CHINA

EP.
2025;
: pp.156-167
1
Jiuquan College of Vocational Technology
2
Department of Ecology and Environmental safety, Vinnytsia National Technical University
3
Department of Biology, Vinnytsia Mykhailo Kotsiubynskyi State Pedagogical University

An environmental impact of waste batteries was analysed (focusing on certain types like nickel-cadmium, lead-acid batteries). The study also adopts a quantitative analysis method, combined with China's battery production, sales, import and export data (2014–2023), and obtains data through the United Nations Commodity Trade Database and the China Battery Association report. The Weibull life distribution model was used to estimate the waste battery generation in China. The calculation is also based on the average lifetime and recycling rate of batteries. China's imports of batteries generally showed a downward trend, while exports showed an upward trend, especially lithium batteries (both primary and lithium-ion rechargeable). With a constant increase in batteries production, amount of batteries on Chinese market has grown during last 10 years, although some battery types (lead-acid, nickel-cadmium) demonstrate reduction due to the replacement with other batteries. According to our calculations, waste lithium batteries (driven by the new energy industry) and lead-acid batteries (huge stock market) are the main contributors to waste battery volume growth, covering 99% of around 10.5 million tons of waste battery generation in China. Further research prospects are to introduce more variables (such as technological progress and consumer habits) to improve the waste battery generation prediction model through dynamic model optimization.

1. China Governmental Portal. (2012). Law of the People's Republic of China on the Prevention and Control of Environmental Pollution by Solid Waste. Retrieved from https://www.gov.cn/bumenfuwu/2012-11/13/content_2601285.htm

2. China Nonferrous Network. (2013). Regulations on limiting the mercury content in battery products. Retrieved from https://www.cnmn.com.cn/ShowNews1.aspx?id=278232

3. Handschuh‐Wang, S., Wang, T., Gancarz, T., Liu, X., Wang, B., He, B., Dickey, M. D., Wimmer, G. W., & Stadler, F. J. (2024). The Liquid Metal Age: A Transition From Hg to Ga. Advanced Materials, 36(45), 2408466. doi: https://doi.org/10.1002/adma.202408466

4. Karpinski, A. P., Russell, S. J., Serenyi, J. R., & Murphy, J. P. (2000). Silver based batteries for high power applications. Journal of Power Sources, 91(1), 77-82. doi: https://doi.org/10.1016/S0378-7753(00)00489-4

5. Kotkunde, K. N., Ashwin, A., Gosavi, A., & Gaur, M. (2021, April). Life Cycle Assessment of Nickel Cadmium Battery. In IOP Conference Series: Materials Science and Engineering, 1123, 1, 012022. IOP Publishing. doi: https://doi.org/10.1088/1757-899X/1123/1/012022

6. Liu-Sullivan, N., & Sullivan, L. R. (2023). Concise Encyclopedia of Green Technology in China. Lanham, USA: Rowman & Littlefield Publishers.

7. Magalini, F., Feng, W., Huisman, J., Kuehr, R., Baldé, K., van Straalen, V., Hestin, M., Lecerf, L., Sayman, U., & Akpulat, O. (2014). Study on Collection Rates of Waste Electrical and Electrical and Electronic Equipment (WEEE). Possible measures to be initiated by the commission as required by article 7(4), 7(5), 7(6) and 7(7) of Directive 2012/19/EU on waste electrical and electronic equipment (WEEE). European Commission.

8. Mrozik, W., Rajaeifar, M. A., Heidrich, O., & Christensen, P. (2021). Environmental impacts, pollution sources and pathways of spent lithium-ion batteries. Energy & Environmental Science, 14(12), 6099-6121. doi: https://doi.org/10.1039/D1EE00691F

9. Ministry of Natural Resources of the People's Republic of China. (2024). China’s dry cell battery industry. Retrieved from https://www.eco.gov.cn/news_info/73943.html

10. Novikova, P. (2022). Environmentally safe management of cadmium and mercury. Case: nickel-cadmium battery and compact fluorescent lamp. Bachelor thesis. Retrieved from https://urn.fi/URN:NBN:fi:amk-2022051810247

11. Ryś, P. A., Siekierski, M., Kłos, M., & Moszczyński, P. (2024). Trends and prospects in lead-acid battery developments. Journal of Power Technologies, 104(1), 67-85.

12. Rehman, K., Fatima, F., Waheed, I., & Akash, M. S. H. (2018). Prevalence of exposure of heavy metals and their impact on health consequences. Journal of cellular biochemistry, 119(1), 157-184. doi: https://doi.org/10.1002/jcb.26234

13. Seabolt Jr, D. G. (1984). United States technology exports to the People’s Republic of China: current developments in law and policy. Texas International Law Journal, 19, 577.

14. Sherman, S. (2019). Improved Electric Vehicle Powertrain Incorporating a Lithium-Ion Battery and a Range Extender Zinc-Air Battery, plus Associated Health and Economic Benefits. Master’s thesis, University of Waterloo. Retrieved from https://dspacemainprd01.lib.uwaterloo.ca/server/api/core/bitstreams/3cc1a0ed-43b5-426c-a8b3-45cd590e9f4c/content

15. Song, X., Hu, S., Chen, D., & Zhu, B. (2017). Estimation of waste battery generation and analysis of the waste battery recycling system in China. Journal of Industrial Ecology, 21(1), 57-69. doi: https://doi.org/10.1111/jiec.12407

16. UN Comtrade database. (2024). Trade data. Retrieved from https://comtradeplus.un.org/TradeFlow

17. Vasant Kumar, R., & Sarakonsri, T. (2023). A Review of Materials and Chemistry for Secondary Batteries. In: Rechargeable Ion Batteries: Materials, Design and Applications of Li‐Ion Cells and Beyond, 49-81. doi: https://doi.org/10.1002/9783527836703.ch3

18. Wang, Q., Liu, W., Yuan, X., Tang, H., Tang, Y., Wang, M., Zuo, J., Song, Z., & Sun, J. (2018). Environmental impact analysis and process optimization of batteries based on life cycle assessment. Journal of cleaner production, 174, 1262-1273. doi: https://doi.org/10.1016/j.jclepro.2017.11.059

19. Wengierek, M. (2021). Technical and organisational conditions in the management of recovery and recycling processes of waste batteries and accumulators. Organization and Management, 1, 137-157. doi: http://dx.doi.org/10.29119/1899-6116.2021.53.10

20. Wu, L., Zhang, F. S., Zhang, Z. Y., & Zhang, C. C. (2023). Corrosion behavior and corrosion inhibition performance of spent lithium-ion battery during discharge. Separation and Purification Technology, 306, 122640. doi: https://doi.org/10.1016/j.seppur.2022.122640

21. Yang, M., Sun, X., Liu, R., Wang, L., Zhao, F., & Mei, X. (2024). Predict the lifetime of lithium-ion batteries using early cycles: A review. Applied Energy, 376, 124171. doi: https://doi.org/10.1016/j.apenergy.2024.124171

22. Zhao, W. (2003). A Study on the Environmental Policies of Waste Batteries in China. Master’s thesis. Retrieved from http://lup.lub.lu.se/student-papers/record/1325150/file/1325151.pdf