CHEMICAL SOIL DEGRADATION FROM MILITARY ACTIVITIES: AN INTEGRATED APPROACH TO LAND RECLAMATION

EP.
2025;
: рр. 344-354
1
Sumy State University
2
Sumy State University
3
Limited Liability Company "Scientific and Production Enterprise of Chemical Products"
4
Sumy State University

Soil degradation due to military operations is a pressing environmental problem today, requiring detailed study and application of environmentally safe protection technology. The study of the impact of military operations on the soil was conducted using the example of the Sumy region. The methods of X-ray fluorescence (elemental composition and content of heavy metals – HM) and liquid chromatography (organic explosives content) were used to analyze the selected soil samples. The assessment of the environmental risk from soil contamination with HM was carried out using the potential environmental risk index. The maximum permissible concentration for HM Cr, Sr, Cu, and Zn was found to be exceeded, as well as samples for Mn in some. The distribution of pollution by the values of environmental risk from soil contamination with HM has the form: Cu > Cr > Sr > Zn > Mn, and a low level of environmental risk was found, which is associated with high concentrations of HM in the control sample. In the studied soil samples, explosive residues (hexogen) were detected at a level from 1.38 mg/kg at the epicenter of the explosion to 2.34 mg/kg at a distance of 5 m from the funnel cut. Natural pathways of hexogen degradation have been established, which formed the basis of proposed approaches to process intensification, in particular the use of biosorbents and bacterial consortia. A comprehensive remediation scheme has been developed for contaminated sites, including the use of technologies based on physical, chemical and biological methods.

 

1. Baliuk, S. A., Kucher, A. V., Solokha, M. O., & Solovei, V. B. (2024). Assessment of the impact of armed aggression of the rf on the soil cover of Ukraine. Ukrainian Geographical Journal, 2024(1), 07–18. doi: https://doi.org/10.15407/ugz2024.01.007

https://doi.org/10.15407/ugz2024.01.007

2. Bilyi, T., Hlavatskyi, D., Poliachenko, I., Melnyk, G., Cherkes, S., & Litvinov, D. (2025). The degree of soil degradation and aerosol formation from explosion products resulting from hostilities in Ukraine. Visnyk of Taras Shevchenko National University of Kyiv: Geology, 1(108), 39–46. doi: https://doi.org/10.17721/1728-2713.108.05

https://doi.org/10.17721/1728-2713.108.05

3. Bordeleau, G., Martel, R., Ampleman, G., & Thiboutot, S. (2008). Environmental impacts of training activities at an air weapons range. Journal of Environmental Quality, 37(2), 308–317. doi: https://doi.org/10.2134/jeq2007.0197

https://doi.org/10.2134/jeq2007.0197

4. Broomandi, P., Guney, M., Kim, J. R., & Karaca, F. (2020). Soil contamination in areas impacted by military activities: A critical review. Sustainability, 12(21), 9002. doi: https://doi.org/10.3390/su12219002

https://doi.org/10.3390/su12219002

5. Corredor, D., Duchicela, J., Flores, F. J., Maya, M., & Guerron, E. (2024). Review of Explosive Contamination and Bioremediation: Insights from Microbial and Bio-Omic Approaches. Toxics, 12(4), 249. doi: https://doi.org/10.3390/toxics12040249

https://doi.org/10.3390/toxics12040249

6. Dong, B., Huan, Z., Cai, L., Liu, L., Han, M., Nie, G., Zhao, S., Liu, G., & Zhu, Y. (2024). Biochar applications for efficient removal of energetic compound contaminants. Chemosphere, 364, 143135. doi: https://doi.org/10.1016/j.chemosphere.2024.143135

https://doi.org/10.1016/j.chemosphere.2024.143135

7. Gorecki, S., Nesslany, F., Hubé, D., Mullot, J., Vasseur, P., Marchioni, E., Camel, V., Noël, L., Bizec, B. L., Guérin, T., Feidt, C., Archer, X., Mahe, A., & Rivière, G. (2017). Human health risks related to the consumption of foodstuffs of plant and animal origin produced on a site polluted by chemical munitions of the First World War. The Science of the Total Environment, 599–600, 314–323. doi: https://doi.org/10.1016/j.scitotenv.2017.04.213

https://doi.org/10.1016/j.scitotenv.2017.04.213

8. Hryhorczuk, D., Levy, B. S., Prodanchuk, M., Kravchuk, O., Bubalo, N., Hryhorczuk, A., & Erickson, T. B. (2024). The environmental health impacts of Russia’s war on Ukraine. Journal of Occupational Medicine and Toxicology, 19(1). doi: https://doi.org/10.1186/s12995-023-00398-y

https://doi.org/10.1186/s12995-023-00398-y

9. Illienko, V., Salnikova, A., Klepko, A., & Lazarev, M. (2025). Military soil degradation in the northern part of Ukraine. EGU General Assembly 2025, EGU25-8455..doi: https://doi.org/10.5194/egusphere-egu25-8455

https://doi.org/10.5194/egusphere-egu25-8455

10. Jahandari, A., & Abbasnejad, B. (2024). Environmental pollution status and health risk assessment of selective heavy metal(oid)s in Iran’s agricultural soils: A review. Journal of Geochemical Exploration, 256, 107330. doi: https://doi.org/10.1016/j.gexplo.2023.107330

https://doi.org/10.1016/j.gexplo.2023.107330

11.Jugnia, L., Beaumier, D., Holdner, J., Delisle, S., Greer, C. W., & Hendry, M. (2017). Enhancing the Potential for in situ Bioremediation of RDX Contaminated Soil from a Former Military Demolition Range. Soil and Sediment Contamination an International Journal, 26(7–8), 722–735. doi: https://doi.org/10.1080/15320383.2017.1410097

https://doi.org/10.1080/15320383.2017.1410097

12. Jugnia, L. B., Manno, D., Drouin, K., & Hendry, M. (2018). In situ pilot test for bioremediation of energetic compound-contaminated soil at a former military demolition range site. Environmental Science and Pollution Research, 25(20), 19436–19445. doi: https://doi.org/10.1007/s11356-018-2115-y

https://doi.org/10.1007/s11356-018-2115-y

13. Khan, M. A., Sharma, A., Yadav, S., Celin, S. M., Sharma, S., Noureldeen, A., & Darwish, H. (2021). Enhancing remediation of RDX-contaminated soil by introducing microbial formulation technology coupled with biostimulation. Journal of Environmental Chemical Engineering, 9(5), 106019. doi: https://doi.org/10.1016/j.jece.2021.106019

https://doi.org/10.1016/j.jece.2021.106019

14. Lance, R. F., Butler, A. D., Jung, C. M., & Lindsay, D. L. (2020). Multiple stressors in multiple species: Effects of different RDX soil concentrations and differential water-resourcing on RDX fate, plant health, and plant survival. PLoS ONE, 15(8), e0234166. doi: https://doi.org/10.1371/journal.pone.0234166

https://doi.org/10.1371/journal.pone.0234166

15 .Land resources. (2025). Damage caused. EcoZagroza. Official resource of the Ministry of Environmental Protection and Natural Resources of Ukraine. Retrieved  from https://ecozagroza.gov.ua/en/damage/shove

16 .Lapointe, M., Martel, R., & Diaz, E. (2017). A conceptual model of fate and transport processes for RDX deposited to surface soils of North American active demolition sites. Journal of Environmental Quality, 46(6), 1444–1454. doi: https://doi.org/10.2134/jeq2017.02.0069

https://doi.org/10.2134/jeq2017.02.0069

17. Lapointe, M., Martel, R., & Cassidy, D. P. (2020). RDX degradation by chemical oxidation using calcium peroxide in bench scale sludge systems. Environmental Research, 188, 109836. doi: https://doi.org/10.1016/j.envres.2020.109836.

https://doi.org/10.1016/j.envres.2020.109836

18.  Menshov, O., Bondar, K., Bakhmutov, V., Hlavatskyi, D., & Poliachenko, I. (2024). Magnetic mineralogical properties of Kyiv region soils, affected by war. Visnyk of Taras Shevchenko National University of Kyiv Geology, 3(106), 5–12. doi: https://doi.org/10.17721/1728-2713.106.01

https://doi.org/10.17721/1728-2713.106.01

19. Mystrioti, C., & Papassiopi, N. (2024). A Comprehensive Review of Remediation Strategies for Soil and Groundwater Contaminated with Explosives. Sustainability, 16(3), 961. doi: https://doi.org/10.3390/su16030961

https://doi.org/10.3390/su16030961

20. Oh, S., Yoon, H., Jeong, T., & Kim, S. D. (2015). Evaluation of remediation processes for explosive‐contaminated soils: kinetics and Microtox® bioassay. Journal of Chemical Technology & Biotechnology, 91(4), 928–937. doi: https://doi.org/10.1002/jctb.4658

https://doi.org/10.1002/jctb.4658

21. Petrushka, K., Petrushka, I., & Yukhman, Y. (2023). Assessment of the impact of military actions on the soil cover at the explosion site by the Nemerov Method and the Pearson Coefficient Case study of the City of Lviv. Journal of Ecological Engineering, 24(10), 77–85. doi: https://doi.org/10.12911/22998993/170078

https://doi.org/10.12911/22998993/170078

22. Petrushka, K., Malovanyy, M. S., Skrzypczak, D., Chojnacka, K., & Warchoł, J. (2024a). Risks of Soil Pollution with Toxic Elements During Military Actions in Lviv. Journal of Ecological Engineering, 25(1), 195–208. doi: https://doi.org/10.12911/22998993/175136.

https://doi.org/10.12911/22998993/175136

23. Petrushka, K., Petrushka, I., & Holdrych, A. (2024b). Dynamics of heavy metals migration in the soil as a consequence of military actions. Environmental Problems, 9(2), 109–116. https://doi.org/10.23939/ep2024.02.109

https://doi.org/10.23939/ep2024.02.109

24. Rodrigues, S., Marques, M., Ward, C. R., Suárez-Ruiz, I., & Flores, D. (2012). Mineral transformations during high temperature treatment of anthracite. International Journal of Coal Geology, 94, 191–200. doi: https://doi.org/10.1016/j.coal.2011.09.012

https://doi.org/10.1016/j.coal.2011.09.012

25. Sharma, K., Sharma, P., & Sangwan, P. (2023). Bioremediation of RDX and HMX contaminated soil employing a biochar-based bioformulation. Carbon Research, 2(1). doi: https://doi.org/10.1007/s44246-023-00068-y

https://doi.org/10.1007/s44246-023-00068-y

26. Shebanina, O., Kormyshkin, I., Bondar, A., Bulba, I., & Ualkhanov, B. (2023). Ukrainian soil pollution before and after the Russian invasion. International Journal of Environmental Studies, 81(1), 208–215. doi: https://doi.org/10.1080/00207233.2023.2245288

https://doi.org/10.1080/00207233.2023.2245288

27. Shukla, S., Mbingwa, G., Khanna, S., Dalal, J., Sankhyan, D., Malik, A., & Badhwar, N. (2023). Environment and health hazards due to military metal pollution: A review. Environmental Nanotechnology Monitoring & Management, 20, 100857. doi: https://doi.org/10.1016/j.enmm.2023.100857

https://doi.org/10.1016/j.enmm.2023.100857

28.Skvortsova, P., Ablieieva, I., Boiko, A., Chernysh, Y., Bataltsev, Y., Kuzomenska, K., & Roubík, H. (2025). Assessment of ecological safety and economic efficiency of biosorption technology for soil protection after hostilities. Journal of Hazardous Materials Advances, 100677. doi: https://doi.org/10.1016/j.hazadv.2025.100677

https://doi.org/10.1016/j.hazadv.2025.100677

29 Solokha, M., Demyanyuk, O., Symochko, L., Mazur, S., Vynokurova, N., Sementsova, K., & Mariychuk, R. (2024). Soil Degradation and Contamination Due to Armed Conflict in Ukraine. Land, 13(10), 1614. doi: https://doi.org/10.3390/land13101614

https://doi.org/10.3390/land13101614

30. Via, S. M., & Zinnert, J. C. (2015). Impacts of explosive compounds on vegetation: A need for community scale investigations. Environmental Pollution, 208, 495–505. doi: https://doi.org/10.1016/j.envpol.2015.10.020  

https://doi.org/10.1016/j.envpol.2015.10.020

31. Yang, X., Lai, J., Zhang, Y., Luo, X., Han, M., & Zhao, S. (2021). Microbial community structure and metabolome profiling characteristics of soil contaminated by TNT, RDX, and HMX. Environmental Pollution, 285, 117478. doi: https://doi.org/10.1016/j.envpol.2021.117478

https://doi.org/10.1016/j.envpol.2021.117478

32. Yang, X., Lai, J., Zhang, Y., & Luo, X. (2022). Reshaping the microenvironment and bacterial community of TNT- and RDX-contaminated soil by combined remediation with vetiver grass (Vetiveria ziznioides) and effective microorganism (EM) flora. The Science of the Total Environment, 815, 152856. doi: https://doi.org/10.1016/j.scitotenv.2021.152856.

https://doi.org/10.1016/j.scitotenv.2021.152856

33. Zaitsev, Y., Hryshchenko, O., Romanova, S., & Zaitseva, I. (2022). Influence of combat actions on the content of gross forms of heavy metals in the soils of Sumy and Okhtyrka districts of Sumy region. Agroecological Journal, 3, 136–149. doi: https://doi.org/10.33730/2077-4893.3.2022.266419

https://doi.org/10.33730/2077-4893.3.2022.266419