STUDY OF THE PROCESS OF ADSORPTION OF PETROLEUM PRODUCTS METHODS OF MULTIVARIATE CLUSTER ANALYSIS

1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Jan Dlugosz University in Czestochowa

The article is devoted to studying the process of adsorption of oil products using multivariate cluster analysis methods. The study solves the problem of environmental pollution with petroleum substances and the search for effective cleaning methods. The work aims to study the prospects of using synthetic zeolites to effectively purify industrial wastewater from oil products. The scientific novelty of the study is the study of the potential of synthetic zeolites as adsorbents to ensure an efficient and environmentally friendly process of cleaning industrial wastewater from petroleum products. The adsorption research methodology included selecting and preparing eight types of adsorbents, determining temperature and concentration range, measuring adsorption capacity, data processing and analysis of results. In the experimental study, the photometric method was used, one of the most accurate and widely used methods for measuring the adsorption of petroleum products. The study results indicate some materials potential for the effective adsorption of petroleum products. The study provides grounds for recommendations regarding the optimal conditions for the adsorption process and the selection of materials for further research and development. The application of multivariate cluster analysis in the study of the adsorption process of oil products opens up new opportunities for solving environmental pollution problems and developing effective technologies for cleaning the environment. The outcomes of this study are anticipated to significantly benefit industries dealing with petroleum product separation and pollution control. By offering a more comprehensive understanding of the adsorption process, this research opens avenues for developing tailored adsorption strategies for specific applications.

1. Bai, S., Chu, M., Zhou, L., Chang, Z., Zhang, C., & Liu, B. (2022). Removal of heavy metals from aqueous solutions by X-type zeolite prepared from a combination of oil shale ash and coal fly ash. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 44(2), 5113-5123. doi: https://doi.org/ 10.1080/15567036.2019.1661549

2. Fawaz, E.G., Salam, D.A., S. Rigolet, S., & Daou, T.J. (2021). Hierarchical zeolites as catalysts for biodiesel production from waste frying oils to overcome mass transfer limitations. Molecules, 26(16), 4879. doi: https://doi.org/10.3390/molecules26164879

3. Hayawin, Z.N., Syirat, Z.B., Ibrahim, M.F., Faizah, J.N., Astimar, A.A., Noorshamsiana, A.W., & Abd-Aziz, S. (2023). Pollutants removal from palm oil mill effluent (POME) final discharge using oil palm kernel shell activated carbon in the up-flow continuous adsorption system. International Journal of Environmental Science and Technology, 20(5), 5325-5338. doi: https://doi.org/10.1007/s13762-022-05268-8

4. Hyvlud, A., Sabadash, V., Gumnitsky, J., & Ripak, N. (2019). Statics and kinetics of albumin adsorption by natural zeolite. Chemistry & Chemical Technology, 1(13), 995-100. doi:  https://doi.org/10.23939/chcht13.01.095

5. Melaibari, A.A., Elamoudi, A.S., Mostafa, M.E., & Abu-Hamdeh, N.H. (2023). Waste-to-Energy in Saudi Arabia: Treatment of petroleum wastewaters utilizing zeolite structures in the removal of phenol pollutants by using the power of molecular dynamics method. Engineering Analysis with Boundary Elements, 148, 317-323. doi: https://doi.org/10.1016/j.enganabound.2023.01.003

6. Mohammadi, M., Sedighi, M., & Hemati, M. (2020). Removal of petroleum asphaltenes by the improved activity of NiO nanoparticles supported on green AlPO-5 zeolite: Process optimization and adsorption isotherm. Petroleum, 6(2), 182-188. doi: https://doi.org/10.1016/j.petlm.2019.06.004

7. Mouandhoime, Z.O., & Brouillette, F. (2021). Evaluation of a combination of phosphorylated fibres and zeolite as a potential substitute for synthetic wetting agents in peat moss products. Canadian Journal of Soil Science, 101 (2), 317-323. doi: https://doi.org/10.1139/cjss-2020-0122

8. Roulia, M., Koukouza, K., Stamatakis, M., & Vasilatos, C. (2022). Fly-ash derived Na-P1, natural zeolite tuffs and diatomite in motor oil retention. Cleaner Materials, 4, 100063. doi: https://doi.org/10.1016/j.clema.2022.100063

9. Sabadash, V., Gumnitsky, Y., & Liuta, O. (2020). Investigation of the process of ammonium ion adsorption by natural and synthetic sorbents by methods of multidimensional cluster analysis. Environmental Problems, 5(2), 113-118. doi: https://doi.org/10.23939/ep2020.02.113

10. Samanta, N.S., Das, P.P., Mondal, P., Changmai, M., & Purkait, M.K. (2022). Critical review on the synthesis and advancement of industrial and biomass waste-based zeolites and their applications in gas adsorption and biomedical studies. Journal of the Indian Chemical Society, 99(11), 100761. doi: https://doi.org/10.1016/j.jics.2022.100761

11. Wang, S.H., Yun, Z.U., Qin, Y.C., Zhang, X.T., & Song, L.J. (2020). Fabrication of effective desulfurization species active sites in the CeY zeolites and the adsorption desulfurization mechanisms. Journal of Fuel Chemistry and Technology, 48(1), 52-62. doi: https://doi.org/10.1016/S1872-5813(20)30003-7

12. Wang, X., You, Y., Han, X., & Jiang, X. (2021). Product distribution and coke formation during catalytic pyrolysis of oil shale with zeolites. Journal of Thermal Analysis and Calorimetry, 147, 8535–8549. doi: https://doi.org/10.1007/s10973-021-11138-x

13. Wang, Z., & Chen, X.F. (2021). A periodic density functional theory study on methanol adsorption in HSAPO-34 zeolites. Chemical Physics Letters, 771, 138532. doi: https://doi.org/10.1016/j.cplett.2021.138532

14. Wiśniewska, M. (2023). Water-Soluble Polymers as Substances Modifying the Stability of Colloidal Systems, the Nanostructure of Adsorption Layers. In Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications: Selected Proceedings of the IX International Conference Nanotechnology and Nanomaterials (NANO2021), 25–28 August 2021, Lviv, Ukraine, 551-568. Cham: Springer International Publishing. doi: https://doi.org/10.1007/978-3-031-18096-5_33