Styrene–butadiene–styrene triblock copolymer (SBS) blends were prepared using different weight ratios of conducting polyaniline (PANI). Several electrical properties such as volume resistivity, dielectric constant, dissipation factor and alternating current conductivity of the blends were studied pointing to understand the influence of different parameters like PANI concentration, frequency, and temperature on these properties. The prepared materials present a slight reduction in volume resistivity as a function of temperature, being useful in conditions where the temperature control is hard. More than this, dielectric constant tests allowed inferring that among tested samples, the one filled with 45 wt % of PANI is potentially able to be used in the electromagnetic dissipation field. Finally, the alternating current tests allowed to prove that the electrical conduction of the blend is mainly dominated by ionic transportation. Therefore, prepared materials can be considered as a strategic, low-cost, environmentally friendly material which can be used in various border fields.
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