координаційні сполуки

Investigation of Coordination Compounds of Gadolinium (III) With β-Diketones

New coordination compounds of gadolinium with $\beta$-diketones  containing  unsaturated and aliphatic or aromatic substituents in the $\alpha$-positions of the chelate ring have been synthesized. The performed quantum-chemical calculations of ligand molecules indicate the best acceptor properties of ligands with aromatic substituents.

Synthesis, Structure and Application of Mixed-Ligand Coordination Compounds of Copper(II) with Substituted Thioamides

New coordination compounds of copper(II) with substituted thioamides of the general formula [Cu(HL6-9)2X2]2 and CuL26-9 have been synthesized. The consecutive reaction of nucleophilic substitution/elimination of SN1/E1 in the octahedral complex [Cu(NH3)4Cl2]•H2O and catalytic hydrolysis of [Cu(HL6-9)2X2]2 complexes have been investigated.