reaction mechanism

The mechanism of diepoxide and adipic acid (AA) reaction in the presence of benzyltriethylammonium chloride and 1,4-diazobicyclo[2,2,2] octane has been proposed. The thermal stability of the oligoester obtained via chemical modification of the dioxydiphenylpropane diglycidyl ether with AA and epoxy-oligoesteric mixtures with its participation has been studied. The viscoelastic properties of films based on epoxy-oligoesteric mixtures containing Epidian-5 epoxy resin, TGM-3 oligoesteracrylate, AA modified Epidian-5 and polyethylpolyamine have been determined.

Mercury selenide (HgSe) films were obtained on glass substrates via the chemical deposition method. The aqueous solutions of mercurium(II) nitrate, potassium iodide and sodium selenosulfate were used. Film samples obtained at two temperatures of synthesis were analyzed by X-ray and structural analysis. The effect of the deposition duration on the optical and morphological properties of HgSe films was investigated. The deposition mechanism was discussed.

The interaction of Os(IV) ions with morin, quercetin, luteolin has been investigated and the spectrophotometric methods of osmium determination using these reagents have been elaborated. The influence of various factors and the maximum yield of the products of Os(IV) ions interaction with flavonoids have been determined.