тверді розчини

Relevance of the development of high-strength glass-ceramic coatings obtained by resource-saving technology for protective elements has been established. Structure formation mechanism in magnesium aluminosilicate glasses during heat treatment has been analyzed. Selection of the system was substantiated, model glasses and glass-ceramic materials on its base have been developed. Patterns of structure regularity and formation of the phase composition of glass-ceramic materials during their ceramization have been investigated.

The character of the interaction in the TlAs2Se3Te–TlAs2Te3Se system was studied by the methods of DTA, RFA, MSA, and also by measuring the microhardness and determining the density. State diagram of the system was constructed. It was established that the TlAs2Se3Te–TlAs2Te3Se system is partially a quasibinary section of the quaternary As, Tl//Se, Te system. One congruently melting compound TlAs2Se2Te2 is formed in the system at 548 K.

Liquid phase technologies for high-grade ceramic oxide powders of technical purpose and methods of their modification have been developed. On the basis of physico-chemical research methods various mechanisms of modifying processes have been analyzed. Substitution of the main ions by doping ones occurs in complex oxide powders followed by the formation of solid solutions. A powder which was obtained via TiO2 modification by sulfur has a surface layer in which sulfur forms chemical bonds.