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  3. Volume 4, Number 2
  4. TECHNOLOGICAL FEATURES OF OBTAINING AND PROPERTIES OF GRAFTED POLYVINYLPYRROLIDONE COPOLYMERS

TECHNOLOGICAL FEATURES OF OBTAINING AND PROPERTIES OF GRAFTED POLYVINYLPYRROLIDONE COPOLYMERS

CTAS.
2021;
Volume 4, Number 2
: 210-216
https://doi.org/10.23939/ctas2021.02.210
Authors:
  1. Victoria Zemke
  2. Nataliia Chopyk
  3. U. V. Khromyak
  4. Volodymyr Levytskyi
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University, The John Paul II Catholic University of Lublin

The impact of the vinyl monomers nature, concentration, and temperature on the kinetics of dispersion polymerization in the presence of polyvinylpyrrolidone was studied. The optimal technological parameters of the copolymer synthesis process are determined. It is defined that the properties of dispersion polymerization depend on the process conditions. Such conditions are temperature, monomer and aqueous phase ratio, monomer and initiator concentrations and as well as the amount of polyvinylpyrrolidone. Presented materials derived on the ground of the developed compositions are characterized by principally high working and physical-mechanical properties.

aqueous phase
methylmethacrylate
copolymer
polyvinylpyrrolidone
dispersion polymerization
vinyl monomers

1. Long A. C. (2007) Composites forming technologies. Cambridge: Woodhead Publishing House, 344.
https://doi.org/10.1533/9781845692537
2. Rakesh K. Gupta, Elliot Kennel, Kwang-Jea Kim (2009). Polymer Nanocomposites Handbook. Cambridge: CRC Press.
https://doi.org/10.1201/9781420009804
3. K. Chen-Yu, L. Tzu-Chiang, L. Wen-Chie (2203) Influence of polyvinylpyrrolidone on the hydrophobic properties of partially porous poly(styrene-divinylbenzene) particles for biological applications / J. Appl. Polym. Sci. 87 (11), 1818-1824.
https://doi.org/10.1002/app.11653
4. Bianco Gilmene, Gehlen Marcelo H. (2002) Synthesis of poly(N-vinyl-2-pyrrolidone) and copolymers with methacrylic acid initiated by the photo-Fenton reaction. J. Photochem. and Photobiol. 13, 115-119.
https://doi.org/10.1016/S1010-6030(01)00641-4
5. Novikov M. B., Roos A., Creton C. (2003) Dynamic mechanical and tensile properties of poly(N-vinylpyrrolidone)-poly(ethyleneglycol) blends / Polymer, (44) 12, 3561-3578.
https://doi.org/10.1016/S0032-3861(03)00132-0
6. Feldstein M. M.,. Shandryuk N. A. Plate N. A (2001) Relation of glass transition temperature to the hydrogen-bonding degree and energy in poly(N-vinylpyrrolidone) blends with hydroxyl-containing plasticizers. Part 1. Effects ofhydroxyl group number in plasticizer molecule /  Polymer.  42 (3), P. 971-979.
https://doi.org/10.1016/S0032-3861(00)00445-6
7. Feldstein M. M., Shandryuk G. A.,. Kuptsov S. A, Plate N. A. (2000) Coherence of thermal transitions in poly(N-vinylpyrrolidone) - poly(ethyleneglycol) compatible blends 3. Impact of sorbed water upon phase behaviour / Polymer. 41 (14), 5349-5359.
https://doi.org/10.1016/S0032-3861(99)00681-3
8. Kuo S. W., Chang F. C. (2001) Studies of miscibility behavior and hydrogen bonding in blends of poly(vinylphenol) and poly(vinylpyrrolidone) / Macromolecules. .34 (15), 5224-5228.
https://doi.org/10.1021/ma010517a
9. Trong N. Q. Loic L. B., Jean N. (1985) Preparation of membranes from polyacrylonitril-polyvinylpyrrolidone blends and the study of their behaviour in the pervaporation of water-organic liquid mixtures / J. Membr. Sci. - 85 (22), 245-255.
https://doi.org/10.1016/S0376-7388(00)81284-3
10. Khromiak U., Levytskyi V., Stepova K., Tarnawsky A. (2018) Synthesis and properties of adhesive polymer-methylmethacrylate materials / International Journal of Polymer Science, 1-9. https://doi.org/10.1155/2018/4905304.
https://doi.org/10.1155/2018/4905304
11. Zaccaron C. M., Oliveira R. V., Guiotoku M. (2005) Blends of hydroxypropyl methylcellulose and poly(l-vinylpyrrolidone-co-vinyl acetate): miscibility and thermal stability / Polym. Degrad. and Stab. - 90 (1), 21-27.
https://doi.org/10.1016/j.polymdegradstab.2005.02.010
12. Khromyak U. V., Levytskyi V. Ye., Stepova K. V., Skorokhoda V. Y. (2018) Synthesis and properties of composites based on copolymers of polyvinylpyrrolidone and methylmethacrylate / Voprosy Khimii i Khimicheskoi Tekhnologii 4, 135-141. DOI: 10.1037/aca0000211 http://oaji.net/articles/2017/1954-1531896702.pdf
https://doi.org/10.1037/aca0000211
13. Levytskyi Volodymyr, Khromiak Ulyana, Skorokhoda Volodymyr, Levytska Khrystyna,MelnykYurii (2018) Technological aspects of obtaining and properties of polyvinylpyrrolidone copolymers and composites; Technological and design aspects of the processing of composites and nanocomposites. Monography, Vol. I: [Ed.]: SikoraJanusz, DulebováĽudmila. Košice: TechnicalUniversityofKošice, 162-174. ISBN 978-80-553-2773-0.