Еffect of synthetic calcium hydrosilicate on the hydration of portland cement

2024;
: 35-41
1
Department of Chemical Technology of Silicates
2
Lviv Polytechnic National University

The regularities of the synthesis of calcium hydrosilicates of tobermorite composition in the system "amorphous silica – calcium hydroxide – water" were investigated. The effect of calcium hydrosilicates additive on the hydration processes of Portland cement and the nature of changes in the strength of cement stone at different stages of its hardening was studied. The methods of determining the heat of hydration of cement dough during hardening and X-ray phase analysis showed that the addition of calcium hydrosilicates at the initial stages of hardening accelerates the physicochemical processes of hydration of clinker minerals.

1. Hewlett, P. C., Liska, M. (2019). Leas chemistry of cement and concrete. Oxford, Butterworth-Heinemann.
2. Kurdowski, W. (2014). Cement and concrete chemistry. Springer Netherlands.
https://doi.org/10.1007/978-94-007-7945-7
3. Kurdowski, W. (1991). Chemia cementu. Warsaw: PWN.
4. Shtark, Y., Vykht, B. (2008). Tsement y yzvest. Kyiv.
5. Runova, R. F., Dvorkin, L. Y., Dvorkin, O. L., Nosovskyi, Yu. L. (2012). Viazhuchi materialy. Kyiv, Osnova.
6. Sanytsky, M., Kropyvnytska, T., Ivashchyshyn, H. (2023). Sustainable modified pozzolanic supplementary cementitious materials based on natural zeolite, fly ash and silica fume. IOP Conf. Series: Earth and Environmental Science. doi:10.1088/1755-1315/1254/1/012004
https://doi.org/10.1088/1755-1315/1254/1/012004
7. Sroda, B. (2017). Potencial przemyslu cementowego w redukcji emisji CO2. Budownictwo, technologie, architektura. 3 (79), 72-74.
8. Andrew, R. M. (2018). Global CO2 emissions from cement production. Earth Syst. Sci. Data, 10, 195-217. doi.org/10.5194/essd-10-195-2018
https://doi.org/10.5194/essd-10-195-2018
9. Sanytskyy, М., Sobol, Kh., & Маrkiv, Т. (2010). Моdyfikovani kompozycijni cementy. Lviv: Vydavnytstvo Lvivskoj politehniky, 132/
10. Zahrai, A. I., Borovets, Z. I., Novitskyi, Ya. M., Chekailo, M. V., Yakymechko, Ya. B. (2019). The effect of dispersed lime on the hardening of cement stone. Khimiia, tekhnolohiia rechovyn ta yikh zastosuvannia, 2 (2), 55-61. https://doi.org/10.23939/ctas2019.02.055
https://doi.org/10.23939/ctas2019.02.055
11. Zahrai, A. I., Borovets, Z. I., Lutsyuk, I. V., Novitskyi, Ya. M. (2020). Kryterii doslidzhennia protsesu dysperhuvannia systemy hidratne vapno-voda. Chemistry, Technology and Application of Substances, 3 (2), 23-27. https://doi.org/10.23939/ctas2020.02.023
https://doi.org/10.23939/ctas2020.02.023
12. Zahrai, A. I., Borovets, Z. I., Lutsyuk, I. V., Novitskyi, Ya. M. (2021).Vstanovlennia optymalnykh parametriv vibroaktyvuvannia hidratnoho vapna. Pytannia khimii ta khimichnoi tekhnolohii, 6 (139), 25-31. http://dx.doi.org/10.32434/0321-4095-2021-139-6-25-31
https://doi.org/10.32434/0321-4095-2021-139-6-25-31
13. Yakymechko, Ya., Lutsyuk, I., Jaskulski, R., Dulnik, J., Kropyvnytska, T. (2020). The Effect of Vibro-Activation Time on the Properties of Highly Active Calcium Hydroxide. Buildings, 10 (111), 1-8. https://doi.org/10.3390/buildings10060111
https://doi.org/10.3390/buildings10060111