reduction

The kinetic characteristics of the reaction of nickel precipitation by hypophosphites in the volume of the solution were studied, depending on the pH of the medium, temperature, oxidant content, nature and concentration of the activator, and the presence of a water-soluble polymer –polyvinylpyrrolidone (PVP). It was found that the presence of PVP in the solution affects the duration of the induction period and the rate of the reduction reaction, and the nature of the effect of PVP significantly depends on the pH of the medium.

The effect of low-pressure glow discharge on the formation of peroxide and the degree of oxidation of Mn, Cr and Fe was studied in the aqueous solutions of different compounds. The plasma treatment causes the reduction of Mn(VII) through Mn(IV) to Mn(II), Cr(VI) to Cr(III) and oxidation of Fe(II) to Fe(III). Among other reactive species, peroxide formed under the action of plasma treatment takes an active part in redox reactions. The concentration of peroxide usually increases with treatment time, but its presence is detected only after completion of active redox processes.

In this article optimal reduction models are presented. Peculiarities of their use in the process of decomposition tasks and complex system modelling are described.The influence of tht problem model on the designing result is analysed.

The GOCE mission has produced gravity gradient data during 2009–2013 years. Various data sets were obtained, such as: tensor of second derivatives in different systems, satellite orbit parameters, the models of the gravitational field of the Earth. In contrast to the direct approach, space-wise-approach, and time-wise approach the construction of the spherical grid of gradients were orthogonality relationships are carry out, was developed via upward/downward continuation to sphere. This paper considers the vertical gravity gradients zz V (EGG TRF2 [Gruber Th., 2010]) in particular.