Recycling of bentonites after their use in wastewater treatment: a review of environmental, sustainability and science

This paper reviews current trends in the reuse and effective disposal of bentonite clay sorbent (montmorillonite, as the main mineral in bentonite and palygorskite clays) after its application in wastewater treatment systems. Special attention is given to its potential applications in construction and polymer composites. A comparative analysis of the advantages and limitations of various approaches to bentonite regeneration, reuse possibilities, and effective disposal of the spent sorbent is conducted. The specifics of using spent bentonite are determined based on the nature of the pollutants sorbed onto the clay mineral surface. Important aspects of using montmorillonite clays, both pristine and pollutant-saturated, are discussed from the perspective of their natural sources, chemical structure, physical and chemical properties. Useful properties for industrial applications include, among others, particle size and layered structure, molecular structure and cation exchange effect, barrier properties, and water absorption. The presented data on the use of spent montmorillonite clays are based on products classified by their industrial application. Most discussions are supported by specific studies and their results.

1. Abdelbasir, S. M., Hassan, S. S. M., Kamel, A. H., & Seif El-Nasr, R. (2018). Status of electronic waste recycling techniques: A review. Environmental Science and Pollution Research. https://doi.org/10.1007/s11356-018-2136-6

2. Andreyeva, O. A., Okhmat, O. A., & Mokrousova, O. R. (2018). Innovative ways to improve the environmental friendliness of tanneries. Visnyk Khmelnytsʹkoho natsionalnoho universytetu, 265(5).

3. Andronov, V., Danchenko, Y., Popovych, V., Bosak, P., Tarnavskyi, A., & Lavrivskyi, M. (2025). Efficiency of using mineral sorbents for purifying natural waters from ammonium ions. Ecological Engineering & Environmental Technology, 26(7), 376–383. https://doi.org/10.12912/27197050/205561

4. Arasu, N. A., Manickaraj, K., Sheik Mohamed Anas, M., & Siddharthan, P. (2025). A review of sustainable construction and waste management: Brick manufacturing using agro-industrial wastes. Zastita Materijala, 66, 1–11. https://doi.org/10.62638/ZasMat1354

5. Bergaya, F., Theng, B. K. G., & Lagaly, G. (Eds.). (2006). Handbook of clay science. Elsevier Ltd. Retrieved from https://ftp.idu.ac.id/wp-content/uploads/ebook/tdg/TERRAMECHANICS%20AND%...(%20PDFDrive%20).pdf

6. Bolshanina, S., Gurets, H., Balabuha, D., & Milyayeva, D. (2014). Sewage treatment by sorption methods in galvanic productions. Environmental Safety, 1(17), 114–118. Retrieved from https://oaji.net/pdf.html?n=2015/1727-1427195905.pdf

7. Chayka, O. H., Zakharko, Y. M., & Khomko, N. Y. (2005). Ochyshchennya vidpratsʹovanoyi olyvy vid smol ta asfalʹteniv za dopomohoyu pryrodnoho dyspersnoho sorbentu-bentonitu. Visnyk “Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya”, 529, 194–196.

8. Da Silva, A., & De Souza, A. (2022). Incorporation of bentonite mining waste in ceramic formulations. Sustainability, 14, 15973. https://doi.org/10.3390/su142315973

9. Di Prima, G., Belfiore, E., Migliore, M., Scarpaci, A. G., Angellotti, G., Restivo, I., Allegra, M., Arizza, V., & De Caro, V. (2022). Green extraction of polyphenols from waste bentonite to produce functional antioxidant excipients for cosmetic and pharmaceutical purposes: A waste-to-market approach. Antioxidants, 11, 2493. https://doi.org/10.3390/antiox11122493

10. Gupta, V. K., Ali, I., Saleh, T. A., Nayak, A., & Agarwal, S. (2012). Chemical treatment technologies for waste-water recycling – an overview. RSC Advances, 2, 6380–6388. https://doii.org/10.1039/c2ra20340e

11. Halysh, V., Trus, I., Nikolaichuk, A., Skiba, M., Radovenchyk, I., Deykun, I., Vorobyova, V., Vasylenko, I., & Sirenko, L. (2020). Spent biosorbents as additives in cement production. Journal of Ecological Engineering, 21(2), 131–138. https://doi.org/10.12911/22998993/116328

12. Jin, H., Reed, D. W., Thompson, V. S., Fujita, Y., Jiao, Y., Crain-Zamora, M., Fisher, J., Scalzone, K., Griffel, M., Hartley, D., & Sutherland, J. W. (2019). Sustainable bioleaching of rare earth elements from industrial waste materials using agricultural wastes. ACS Sustainable Chemistry & Engineering, 7(18), 15311–15319. https://doi.org/10.1021/acssuschemeng.9b02584

13. Kochubei, V., Yaholnyk, S., Bets, M., & Malovanyy, M. (2020). Use of activated clinoptilolite for direct dye-contained wastewater treatment. Chemistry & Chemical Technology, 14, 386–393. https://doi.org/10.23939/chcht14.03.386

14. Kochubei, V., Yaremchuk, Y., Malovanyy, M., Yaholnyk, S., & Slyuzar, A. (2023). Perspectives of treatment of water environments from pollutants with ultrasound-activated bentonites. Chemistry & Chemical Technology, 17(4), 870–877. https://doi.org/10.23939/chcht17.04.870

15. Kontsur, A. Z., Karpyak, A. R., & Sysa, L. V. (2016). Some peculiarities of bentonite regeneration by means of using high-frequency emanation (on the example of biogenic ions). Naukovyy Visnyk NLTU Ukrayiny, 268, 292–297.

16. Kontsur, A., Sysa, L., & Shevchuk, L. (2018). Use of microwaves to activate bentonite in the processes of sorption of nickel ions from concentrated aqueous solutions. Physics and Chemistry of Solid State, 19(2), 191–196. https://doi.org/10.15330/pcss.19.2.191-196

17. Krzemińska, S., & Rzymski, W. M. (2012). Wpływ glinokrzemianów warstwowych na właściwości barierowe kauczuku butylowego. Polimery, 57(7–8), 551–557. Retrieved from https://www.researchgate.net/publication/259532580_Wplyw_glinokrzemianow...

18. Kryklyvyi, R., Sakalova, H., Petrushka, K., & Luchyt, L. (2022). Use of clay sorptive materials in the synthesis of polymer materials. Environmental Problems, 7(1), 18–22. https://doi.org/10.23939/ep2022.01.018

19. Kuziyev, Y., & Abdiyev, Z. (2024). The importance of bentonite clays in the cultivation of agricultural crops. Tajik Journal of Agriculture and Biological Sciences, 5(1), 102–106. Retrieved from https://zienjournals.com/index.php/tjabs/article/view/5781

20. Malovanyy, M., Chornomaz, N., & Nahurskyy, O. (2013). Water sorption purification from ammonium pollution. Chemistry & Chemical Technology, 7(3), 355–358.

21. Malovanyy, M., Zakhariv, O., Kanda, M., Bratashchuk, A., Sakalova, H., Odnorih, Z., & Chornomaz, N. (2016). Syntez prolonhovanykh dobryv shlyakhom adsorbtsiyi elementiv zhyvlennya te mikroelementiv pryrodnymy sorbentamy z promyslovykh ta silʹsʹkohospodarsʹkykh vidkhodiv. Naukovyy Visnyk Natsionalʹnoho Universytetu Bioresursiv ta Pryrodokorystuvannya Ukrayiny, 240, 168–175.

22. Malovanyy, M., Sakalova, H., Vasylinych, T., & Kryklyvyi, R. (2019). The research on the ammonium concentrations in city stocks and further sedimentation of ion-exchange concentrate. Journal of Ecological Engineering, 20, 158–164. https://doi.org/10.12911/22998993/93944

23. Malovanyy, M., Moroz, O., Hnatush, S., Maslovska, O., Zhuk, V., Petrushka, I., Nykyforov, V., & Sereda, F. (2019). Perspective technologies of the treatment of the wastewaters with high content of organic pollutants and ammoniacal nitrogen. Journal of Ecological Engineering, 20(2), 8–15. https://doi.org/10.12911/22998993/94917

24. Malovanyy, M., Palamarchuk, O., Trach, I., Petruk, H., Sakalova, H., Soloviy, K., Vasylinych, T., Tymchuk, I., & Vronska, N. (2020). Adsorption extraction of chromium ions (III) with the help of bentonite clays. Journal of Ecological Engineering, 21(7), 178–185. https://doi.org/10.12911/22998993/125545

25. Malovanyy, M., Blazhko, O., Sakalova, H., & Vasylinych, T. (2021). Ecological aspects of clay sorption materials usage in leather and fur production technologies. Materials Science Forum, 1038, 276–281. https://doi.org/10.4028/www.scientific.net/MSF.1038.276

27. Malovanyy, M., Moroz, O., Popovych, V., Kopiy, M., Tymchuk, I., Sereda, A., Krusir, G., & Soloviy, C. (2021). The perspective of using the “open biological conveyor” method for purifying landfill filtrates. Environmental Nanotechnology, Monitoring & Management, 16, 100611. https://doi.org/10.1016/j.enmm.2021.100611

28. Malovanyy, M., Bordun, I., Sakalova, H., Blazhko, A., & Beznosiuk, N. (2022). Adsorption purification of wastewater from chrome ions and phosphate ions with bentonite. Key Engineering Materials, 925, 111–116. https://doi.org/10.4028/p-8vmxtc

29. Marukhlenko, M., Mokrousova, O., & Okhmat, O. (2017). New tanning agent with montmorillonite for leather manufacturing. Solid State Phenomena, 267, 52–57. https://doi.org/10.4028/www.scientific.net/SSP.267.52

30. Michalska, A. (2016). Wpływ dodatku napełniaczy na sieciowanie mieszanin kauczuków chloroprenowego i butadieno-styrenowego. Tygiel. Retrieved from http://bc.wydawnictwo-tygiel.pl/public/assets/111/Fizyczne, %20chemiczne%20i%20biologiczne%20aspekty%20nauki %20v.3.2.pdf 

31. Mokrousova, E., Dzyazko, Y., Volfkovich, Y., & Nikolskaya, N. (2016). Hierarchical structure of derma affected by chemical treatment and filling with bentonite. In Nanophysics, nanophotonics, surface studies, and application (pp. 277–290). https://doi.org/10.1007/978-3-319-30737-4_23

32. Mokrousova, O. (2017). The organo-mineral composition for retanning–filling of leather semi-finished item. In 3rd International Conference on Advanced Materials and Systems (pp. 85–90). Retrieved from https://surl.li/kzylww

33. Mokrousova, O., Danylkovych, A., & Palamar, V. (2020). Resourse-saving chrome tannage of leather with modified montmorillonite. In A. Danylkovych & O. Korotych (Eds.), Resourse-saving technologies for the production of elastic leather materials (pp. 119–129). Baltija Publishing. Retrieved from https://er.knutd.edu.ua/handle/123456789/1966

34. Palamar, V. A., Marukhlenko, M. O., & Mokrousova, O. R. (2015). Zastosuvannya khrom-modyfikovanykh dyspersiy montmorylonitu dlya stabilizatsiyi kolahenovoyi struktury dermy. Vostochno-Evropeyskyy Zhurnal Peredovykh Tekhnolohyy, 3(6[75]), 36–42. https://doi.org/10.15587/1729-4061.2015.44238

35. Paszkiewicz, S., Walkowiak, K., & Barczewski, M. (2024). Biobased polymer nanocomposites prepared by in situ polymerization: Comparison between carbon and mineral nanofillers. Journal of Materials Science, 59(30), 1–19. https://doi.org/10.1007/s10853-024-10025-8

36. Petrus, R., & Warchoł, J. (2001). Tanie materiały sorpcyjne stosowane do usuwania metali ciężkich z roztworów wodnych. Ecological Chemistry and Engineering, 7(8), 667–678.

37. Petrushka, I. M., & Tarasovych, O. D. (2013). Vykorystannya vidpratsovanykh sorbentiv dlya vyrobnytstva budivelnykh materialiv. Visnyk Natsionalnoho Universytetu Lvivskoyi Politekhniky, 755, 305–308.

38. Petrushka, I. M., Zakharko, Y. M., & Korolko, S. V. (2009). Vykorystannya vidpratsovanykh pryrodnykh sorbentiv, nasychenykh barvnykamy, u budivelniy haluzi. Visnyk NU – Lvivska Politekhnika. Khimiya, Tekhnolohiya Rechovyn ta Yikh Zastosuvannya, 644, 189–191.

39. Polyvanyi, S., Polyvana, A., Sakalova, H., Shevchuk, O., Khodanitska, O., Tkachuk, O., Matviichuk, O., Knyazuk, O., Stepanenko, I., & Zavalnyu, O. (2022). Influence of chlormequat chloride on morphogenesis and productivity of cruciferous plants. Journal of Ecological Engineering, 23(9), 53–60. https://doi.org/10.12911/22998993/151516

40. Reddy, M. A. K., & Rao, V. R. (2019). Utilization of bentonite in concrete: A review. International Journal of Recent Technology and Engineering, 7(6C2).

41. Rengaraj, S., Yeon, K.-H., Kang, S.-Y., Lee, J.-U., Kim, K.-W., & Moon, S.-H. (2002). Studies on adsorptive removal of Co(II), Cr(III) and Ni(II) by JRN77 cation-exchange resin. Journal of Hazardous Materials, B92, 185–198.

42. Rymar, S. I. (2013). Ustanovka dlya reheneratsiyi sorbentiv v elektromahnitnomu poli. Visnyk Natsionalnoho Tekhnichnoho Universytetu, 33(1066), 66–70.

43. Sabadash, V., Nowik-Zając, A., & Gumnitsky, J. (2025). Adsorption of Pb2+ and Zn2+ ions from aqueous solutions with natural zeolite. Journal Environmental Problems, 10(2), 191–196. https://doi.org/10.23939/ep2025.02.191

44. Saidov, B. Y., Alimov, U. K., Ahmadzhonov, A. N., Seytnazarov, A. R., & Namazov, S. S. (2020). The question of the prospects for the use of bentonite clay as a sorbent for the purification of various types of solutions: Short review. International Journal of Applied Natural Sciences, 1, 23–29. https://doi.org/10.24412/2181-144X-2020-1-23-30

45. Sakalova, H., Vasylinych, T., Koval, N., & Kashchei, V. (2017). Investigation of the method of chemical desorption for extraction of nickel ions (II) from bentonite clays. Environmental Problems, 2(4), 187–191.

46. Sakalova, H. V., Kryklyvyi, R. D., & Trach, I. A. (2022). Vykorystannya hlynystykh sorbtsiynykh materialiv v tekhnolohiyakh vyrobnytstva kauchukiv. Visnyk VPI, 2, 23–27. https://doi.org/10.31649/1997-9266-2022-161-2-23-27

47. Sandul, O., Titov, T., Kulyk, A., Sakalova, H., Shevchyk, K., & Petrushka, K. (2024). Reuse of the spent sorbent mixture for wastewater treatment. Journal Environmental Problems, 9(4), 193–198. https://doi.org/10.23939/ep2024.04.193

48. Soloviy, C., Malovanyy, M., Palamarchuk, O., Trach, I., Petruk, H., Sakalova, H., Vasylinych, T., & Vronska, N. (2021). Adsorption method of purification of stocks from chromium (III) ions by bentonite clays. Journal of Water and Land Development, 48, 99–104. https://doi.org/10.24425/jwld.2021.136152

49. Srinivasan, A., & Viraraghavan, T. (2010). Decolorization of dye wastewaters by biosorbents: A review. Journal of Environmental Management, 91(10), 1915–1929. https://doi.org/10.1016/j.jenvman.2010.05.003

50. Sydorchuk, O., Matsuska, O., Sabadash, V., & Gumnitsky, J. (2014). Parallel-serial adsorption of phosphate ions by natural sorbents. Eastern-European Journal of Enterprise Technologies, 6(72), 56. https://doi.org/10.15587/1729-4061.2014.30874

51. Synelnikov, S., Soloviy, K., Malovanyy, M., Tymchuk, I., & Nahurskyy, O. (2019). Improvement of environmental safety of agricultural systems as a result of encapsulated mineral fertilizers implementation. Journal Environmental Problems, 4(4), 223–228. https://doi.org/10.23939/ep2019.04.222

52. Tóth, A. J., Fózer, D., Mizsey, P., Varbanov, P. S., & Klemeš, J. J. (2022). Physicochemical methods for process wastewater treatment: Powerful tools for circular economy in the chemical industry. Reviews in Chemical Engineering, 7, 1123–1151. https://doi.org/10.1515/revce-2021-0094

53. Tymchuk, I., Malovanyy, M., Shkvirko, O., Chornomaz, N., Popovych, O., Grechanik, R., & Symak, D. (2021). Review of the global experience in reclamation of disturbed lands. Ecological Engineering and Environmental Technology, 22(1), 24–30. https://doi.org/10.12912/27197050/132097

54. Tymchuk, I., Shkvirko, O., Sakalova, H., Malovanyy, M., Dabizhuk, T., Shevchuk, O., Matviichuk, O., & Vasylinych, T. (2020). Wastewater as a source of nutrients for crops growth and development. Journal of Ecological Engineering, 21(5), 88–96. https://doi.org/10.12911/22998993/122188

55. Uddin, F. (2021). Introductory chapter: Montmorillonite clay consumption trend in industry. In Montmorillonite Clay (pp. 1–8). https://doi.org/10.5772/intechopen.101362

56. Warzybok, M., & Warchoł, J. (2018). Synthesis of kaolin-based zeolite Y and its application for adsorption of two carbonyl compound gases. JCEEA, 35(1/18), 13–26. https://doi.org/10.7862/rb.2018.2

57. Zhang, H., Liu, S., & Gao, Z. (2023). Adsorption of Zn(II) from landfill leachate using bentonite. Geoenvironmental Disasters, 10(1), 12. https://doi.org/10.1186/s40677-023-00265-2