Methods of obtaining graphene

2023;
: pp. 1-8
Authors:
1
Lviv Polytechnic National University

Graphene was first obtained at the beginning of the 21st century, and since then various methods have been developed for its synthesis. This variety is explained by the natural layered structure of graphite. A large number of methods is based on the idea of separating graphite layers. They are considered relatively cheap, productive and available in almost all laboratories.

Another group of graphene synthesis methods is based on the concept of creating graphene sheets from individual carbon atoms. These methods are technologically more complex and require appropriate specialized equipment.

Due to the wide range of graphene synthesis methods and their availability, researchers from all over the world can conduct experiments with this unique material in various scientific fields. This makes graphene an extremely promising object for further scientific research.

  1. KS Novoselov, AK Geim, SV Morozov, D. Jiang, Y. Zhang, SV Dubonos, IV Grigorieva, and AA Firsov, "Electric Field Effect in Atomically Thin Carbon Films," Science, vol. 306, pp. 666-669, 2004.
    https://doi.org/10.1126/science.1102896
  2. AL Vázquez de Parga, F. Calleja, B. Borca, MCG Passeggi Jr, JJ Hinarejos, F. Guinea, et al., "Periodically rippled graphene: Growth and spatially resolved electronic structure," Physical Review Letters, vol. 100, pp. 056807, 2008.
    https://doi.org/10.1103/PhysRevLett.100.056807
  3. RM Obodo, I. Ahmad, and FI Ezema, "Introductory Chapter: Graphene and Its Applications," Graphene and Its Applications, 1st ed., IntechOpen, Sep. 11, 2019.
  4. AP Aranga Raju, "Production and Applications of Graphene and Its Composites," Ph.D. dissertation, The University of Manchester, Faculty of Engineering and Physical Sciences, 2015.
  5. SS Shams, R. Zhang, and J. Zhu, “Graphene synthesis: a Review,” Mater. Science-Poland, vol. 33, no. 3, pp. 566–578, Sept. 2015.
    https://doi.org/10.1515/msp-2015-0079
  6. A. Adetayo and D. Runsewe, "Synthesis and Fabrication of Graphene and Graphene Oxide: A Review," Open Journal of Composite Materials, vol. 9, pp. 207-229, 2019.
    https://doi.org/10.4236/ojcm.2019.92012
  7. D. Zhan, L. Sun, ZH Ni, L. Liu, XF Fan, and Y. Wang, “Adv. Funct. Mater., 20, 3504, 2010.”
    https://doi.org/10.1002/adfm.201000641
  8. LM Viculis, JJ Mack, OM Mayer, HT Hahn, and RB Kaner, "Intercalation and Exfoliation Routes to Graphite Nanoplatelets," Journal of Materials Chemistry, vol. 15, pp. 974-978, 2005.
    https://doi.org/10.1039/b413029d
  9. K. Parvez, R. Li, S.R. Puniredd, Y. Hernandez, F. Hinkel, S. Wang, X. Feng, and K. Müllen, "Electrochemically exfoliated graphene as solution-processable, highly conductive electrodes for organic electronics," ACS Nano, vol. 7, no. 4, pp. 3598-3606, Apr. 2013. 
    https://doi.org/10.1021/nn400576v
  10. J. Lu, J.-x. Yang, J. Wang, A. Lim, S. Wang, and K. P. Loh, "One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids," ACS Nano, vol. 3, no. 8, pp. 2367-2375, Aug. 2009."
    https://doi.org/10.1021/nn900546b
  11. Y. Hernandez, V. Nicolosi, M. Lotya, F. M. Blighe, Z. Sun, S. De, I. T. McGovern, B. Holland, M. Byrne, Y. K. Gun'Ko, J. J. Boland, P. Niraj, G. Duesberg, S. Krishnamurthy, R. Goodhue, J. Hutchison, V. Scardaci, A. C. Ferrari, and J. N. Coleman, "High-yield production of graphene by liquid-phase exfoliation of graphite", Nat Nanotechnol, vol. 3, no. 9, pp. 563-568, Sep. 2008.
    https://doi.org/10.1038/nnano.2008.215
  12. B. Jayasena and S. Subbiah, "A novel mechanical cleavage method for synthesizing few-layer graphenes," Nano Express, vol. 6, Article number: 95, Jan. 19, 2011."
    https://doi.org/10.1186/1556-276X-6-95
  13. AV Tyurnina, I. Tzanakis, J. Morton, J. Mi, K. Porfyrakis, BM Maciejewska, N. Grobert, and DG Eskin, "Ultrasonic exfoliation of graphene in water: A key parameter study," Carbon, vol . 168, pp. 737-747, 2020.
    https://doi.org/10.1016/j.carbon.2020.06.029
  14.  G. Mittal, V. Dhand, K.Y. Rhee, S.-J. Park, and W.R. Lee, "A Review on Carbon Nanotubes and Graphene as Fillers in Reinforced Polymer Nanocomposites," Journal of Industrial and Engineering Chemistry, vol. 21, pp. 11-25, 2015.
    https://doi.org/10.1016/j.jiec.2014.03.022
  15. D. Nuvoli, L. Valentini, V. Alzari, S. Scognamillo, S.B. Bon, M. Piccinini, J. Illescas, A. Mariani, "High concentration few-layer graphene sheets obtained by liquid phase exfoliation of graphite in ionic liquid," J. Mater. Chem., vol. 21, no. 10, pp. 3428, 2011..
    https://doi.org/10.1039/C0JM02461A
  16. M. Choucair, P. Thordarson, J. A. Stride, "Gram-scale production of graphene based on solvothermal synthesis and sonication," Nat Nanotechnol, vol. 4, no. 1, pp. 30-33, Jan. 2009.
    https://doi.org/10.1038/nnano.2008.365
  17. M. Terrones, "Sharpening the Chemical Scissors to Unzip Carbon Nanotubes: Crystalline Graphene Nanoribbons," ACS Nano, vol. 4, no. 4, pp. 1775-1781, Apr. 2010.
    https://doi.org/10.1021/nn1006607
  18. D. V. Kosynkin, A. L. Higginbotham, A. Sinitskii, J. R. Lomeda, A. Dimiev, B. K. Price, J. M. Tour, "Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons," Nature, vol. 458, no. 7240, pp. 872-876, Apr. 16, 2009.
    https://doi.org/10.1038/nature07872
  19. L. Jiao, L. Zhang, X. Wang, G. Diankov, and H. Dai, "Narrow graphene nanoribbons from carbon nanotubes," Nature, vol. 458, no. 7240, Apr. 16, 2009.
    https://doi.org/10.1038/nature07919
  20. MSA Bhuyan, MN Uddin, MM Islam, FA Bipasha, and SS Hossain, "Synthesis of Graphene", International Nano Letters, vol. 6, pp. 65-83, 2016.
    https://doi.org/10.1007/s40089-015-0176-1
  21. S. Das, P. Sudhagar, YS Kang, and W. Choi, "Synthesis and Characterization of Graphene," in Carbon Nanomaterials for Advanced Energy Systems, W. Lu, J. Baek, and L. Dai, Eds., John Wiley & Sons, Inc., Hoboken, NJ, pp. 85-131, 2015.
    https://doi.org/10.1002/9781118980989.ch3
  22. A. Chakrabarti, J. Lu, J. C. Skrabutenas, T. Xu, Z. Xiao, J. A. Maguire, and N. S. Hosmane, "Conversion of carbon dioxide to few-layer graphene," Journal of Materials Chemistry, Issue 26, 2011.
    https://doi.org/10.1039/c1jm11227a
  23. "Schematic illustration of CVD method of graphene synthesis. (2019).", https://www.researchgate.net/figure/Schematic-illustration-of-CVD-method....
  24. X. Zhang, J. Qiu, J. Tan, D. Zhang, L. Wu, Y. Qiao, G. Wang, J. Wu, KWK Yeung, and X. Liu, "In-situ growth of vertical graphene on titanium by PECVD for rapid sterilization under near-infrared light", Carbon, vol. 192, pp. 209-218, June 15, 2022.
    https://doi.org/10.1016/j.carbon.2022.02.050
  25. X. Li, W. Cai, J. An, S. Kim, J. Nah, D. Yang, et al., "Large-area synthesis of high-quality and uniform graphene films on copper foils", Science , vol. 324, pp. 1312–1314, 2009.
    https://doi.org/10.1126/science.1171245
  26. N. Shang, P. Papakonstantinou, and M. McMullan, "Catalyst-Free Efficient Growth, Orientation and Biosensing Properties of Multilayer Graphene Nanoflake Films with Sharp Edge Planes", Advanced Functional Materials, vol. 18, no. 21, pp. 3506-3514, 2008.
    https://doi.org/10.1002/adfm.200800951
  27. S. Das, P. Sudhagar, YS Kang, and W. Choi, "Synthesis and Characterization of Graphene," in Carbon Nanomaterials for Advanced Energy Systems, W. Lu, J. Baek, and L. Dai, Eds. , John Wiley & Sons, Inc., Hoboken, NJ, pp. 85-131, 2015.
    https://doi.org/10.1002/9781118980989.ch3
  28. NG Shang, P. Papakonstantinou, M. McMullan, M. Chu, A. Stamboulis, A. Potenza, SS Dhesi, and H. Marchetto, "Catalyst-Free Efficient Growth, Orientation and Biosensing Properties of Multilayer Graphene Nanoflake Films", with Sharp Edge Planes," Advanced Functional Materials, vol. 18, No. 21, pp. 3506-3514, November 2008.
    https://doi.org/10.1002/adfm.200800951
  29. J. Lahiri, TS Miller, AJ Ross, L. Adamska, II Oleynik, and M. Batzill, "Graphene growth and stability at nickel surfaces," New J Phys, vol. 13, 2011.
    https://doi.org/10.1088/1367-2630/13/2/025001
  30. "Handbook of Crystal Growth. Thin Films and Epitaxy: Materials, Processes, and Technology. Volume III, Part B," 1346 Pages, 2016.
  31. A.N. Obraztsov, E.A. Obraztsova, AV Tyurnina, and AA Zolotukhin, "Chemical Vapor Deposition of Thin Graphite Films of Nanometer Thickness," Carbon, vol 45, pp. 2017-2021, 2007.
    https://doi.org/10.1016/j.carbon.2007.05.028
  32. Rasool HI, Song EB, Allen MJ, Wassei JK, Kaner RB, Wang KL, et al. Continuity of graphene on polycrystalline copper. Nano Lett 2010;11:251–6.
    https://doi.org/10.1021/nl1036403