OPTIMIZATION OF THE PEROVSKITE SOLAR CELL STRUCTURE

2024;
: 163-171
1
Lviv Polytechnik National University
2
Lviv Polytechnic National University

An experimental perovskite solar cell (PSC) with the structure Au/Spiro-MeOTAD/CH3NH3PbI3/PEDOT:PSS/ITO was fabricated. The measurements of main photovoltaic characteristics were provided. The current-voltage dependences (I-V curves) were measured conducted in the voltage range from -1V to 1V. During the measurements, the corresponding values were calculated of the short-circuit current density(Jsc) and open-circuit voltage(Uoc) were obtained as 1.23 mA/cm² and 0.19 V, respectively. Subsequently, an analytical model corresponding to this structure was formulated. For modeling the parameters of the perovskite solar cell, the Comsol Multiphysics environment was used, this environment is based on the finite element method. The relevant computations were provided to obtain the corresponding values of the short-circuit current density and open-circuit voltage as 3.29 mA/cm² and 0.2 V, respectively, with the maximum theoretically calculated power of this structure being 0.11 W. The experimental outcomes were juxtaposed with the predictions of the analytical computations, and the modeling results were empirically validated. An analytically accomplished model of the same structure was built by adding an electron transport layer (ETL). An organic material BCP (Bathocuproine) was used as an supplementary ETL layer. During the optimization of the PSC, the main datums were mathematically counted. Such values as the short-circuit current density of 10.17 mA/cm², open-circuit voltage of 1.2 V, and the maximum power value of Au/BCP/Spiro-MeOTAD/CH3NH3PbI3/PEDOT:PSS/ITO structure, which is 3.21 W were rated. A comparison of the volt-ampere characteristics of perovskite cells in dark and light modes was conducted for primary and optimized structures. The main parameters, obtained during the modeling of the experimental sample and subsequent model optimization, were compared. Specifically one of the key parameters of solar cell heterostructures the fill factor was evaluated and found to have increased from 16.52% to 25.00%, respectively. The light-sensitive behavior of the perovskite cell were visibly enhanced.

[1].   Nayak, P. K., Mahesh, S., Snaith, H. J., & Cahen, D. (2019). Photovoltaic solar cell technologies: analysing the state of the art. Nature Reviews Materials, 4(4), 269-285.

[2].   Tao, Q., Xu, P., Li, M., & Lu, W. (2021). Machine learning for perovskite materials design and discovery. npj Computational Materials, 7(1), 23.

[3].   Zhang, L., Mei, L., Wang, K., Lv, Y., Zhang, S., Lian, Y., ... & Ding, L. (2023). Advances in the application of perovskite materials. Nano-Micro Letters, 15(1), 177.

[4].   Rai, N., Rai, S., Singh, P. K., Lohia, P., & Dwivedi, D. K. (2020). Analysis of various ETL materials for an efficient perovskite solar cell by numerical simulation. Journal of Materials Science: Materials in Electronics, 31, 16269-16280.

[5].   Al-Shahri, O. A., Ismail, F. B., Hannan, M. A., Lipu, M. H., Al-Shetwi, A. Q., Begum, R. A., ... & Soujeri, E. (2021). Solar photovoltaic energy optimization methods, challenges and issues: A comprehensive review. Journal of Cleaner Production, 284, 125465

[6].   , Kong, J., Wang, H., Rohr, J. A., Fishman, Z. S., Zhou, Y., Li, M., ... & Taylor, A. D. (2020). Perovskite solar cells with enhanced fill factors using polymer-capped solvent annealing. ACS Applied Energy Materials, 3(8), 7231-7238.

[7].   Chen, Y., Tan, S., Li, N., Huang, B., Niu, X., Li, L., ... & Zhou, H. (2020). Self-elimination of intrinsic defects improves the low-temperature performance of perovskite photovoltaics. Joule, 4(9), 1961-1976.

[8].    Kong, J., Wang, H., Rohr, J. A., Fishman, Z. S., Zhou, Y., Li, M., ... & Taylor, A. D. (2020). Perovskite solar cells with enhanced fill factors using polymer-capped solvent annealing. ACS Applied Energy Materials, 3(8), 7231-7238.

[9].   Hossain, M. K., Toki, G. I., Kuddus, A., Rubel, M. H. K., Hossain, M. M., Bencherif, H., ... & Mushtaq, M. (2023). An extensive study on multiple ETL and HTL layers to design and simulation of high-performance lead-free CsSnCl3-based perovskite solar cells. Scientific Reports, 13(1), 2521.

[10]. Hu, Z., Ran, C., Zhang, H., Chao, L., Chen, Y., & Huang, W. (2023). The current status and development trend of perovskite solar cells. Engineering, 21, 15-19.

[11]. Zanuccoli, M., Semenihin, I., Michallon, J., Sangiorgi, E., & Fiegna, C. (2013). Advanced electro-optical simulation of nanowire-based solar cells. Journal of Computational Electronics, 12, 572-584

[12]. Bin, H., Wang, J., Li, J., Wienk, M. M., & Janssen, R. A. (2021). Efficient Electron Transport Layer Free Small‐Molecule Organic Solar Cells with Superior Device Stability. Advanced Materials, 33(14), 2008429..

[13]. Ismail, Z. S., Sawires, E. F., Amer, F. Z., & Abdellatif, S. O. (2023). Experimentally verified analytical models for the dynamic response of perovskite solar cells using measured I–V and C–V characteristics. Optical and Quantum Electronics, 55(14), 1272.

[14]. Girtan, M., Mallet, R., Socol, M., & Stanculescu, A. (2020). On the physical properties PEDOT: PSS thin films. Materials Today Communications, 22, 100735.

[15]. Ren, G., Han, W., Deng, Y., Wu, W., Li, Z., Guo, J., ... & Guo, W. (2021). Strategies of modifying spiro-OMeTAD materials for perovskite solar cells: a review. Journal of Materials Chemistry A, 9(8), 4589-4625.

[16]. Tawalbeh, M., Al-Othman, A., Kafiah, F., Abdelsalam, E., Almomani, F., & Alkasrawi, M. (2021). Environmental impacts of solar photovoltaic systems: A critical review of recent progress and future outlook. Science of The Total Environment, 759, 143528.

[17]. Zhang, S., & Sun, J. (2023). Design and optimization of ARC solar cell with intrinsic layer and p–n junction in bottom cell under AM1. 5G standard spectrum. Emergent Materials, 6(1), 159-166.

[18]. Elion, G. R. (2020). Electro-optics handbook. CRC Press.

[19]. Chen, R., Long, B., Wang, S., Liu, Y., Bai, J., Huang, S., ... & Chen, X. (2021). Efficient and stable perovskite solar cells using bathocuproine bilateral-modified perovskite layers. ACS Applied Materials & Interfaces, 13(21), 24747-24755.

[20]. Hashemi, M., Minbashi, M., Ghorashi, S. M. B., Ghobadi, A., Ehsani, M. H., Heidariramsheh, M., & Hajjiah, A. (2021). Electrical and optical characterization of sprayed In2S3 thin films as an electron transporting layer in high efficient perovskite solar cells. Solar Energy, 215, 356-366.

[21]. Asgary, S., Moghaddam, H. M., Bahari, A., & Mohammadpour, R. (2021). Role of BCP layer on nonlinear properties of perovskite solar cell. Solar Energy, 213, 383-391.