It is shown that the attachment of macromolecules of the functional oligoperoxides to the planar polymeric surfaces or to the surface of a dispersed phase results in the localization of the peroxide groups on the interface. Designing of interphase layers with a well-defined structure and nature with the use of the peroxydized interphases and grafting reaction “to” and "from" the surface is carried out. The compatibilizing polymeric layers in polymeric blends and the grafting surface layers with special properties are formed.
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