Structural, Morphological and Optical Properties of Nanoproducts of Zirconium Target Laser Ablation in Water and Aqueous SDS Solutions

Authors:

Vyacheslav Karpukhin, Michael Malikov, Tatyana Borodina, George Valyano, Olesya Gololobova and Dmitry Strikanov

Joint Institute of High Temperatures, Russian Academy of Science 13(2), Izhorskaya St., 125412 Moscow, Russian Federation; vtkarp@gmail.com

Structural, morphological and optical properties of nanoproducts of laser ablation of zirconium target in water and aqueous SDS solutions were investigated. Depending on experiment conditions the indicated products can appear as different crystalline phases of zirconia and organic-inorganic composites, which include SDS alkyl chains intercalated between layers of zirconium oxides or hydroxides. The formation of zirconium dioxide-based hollow nano and microstructures is demonstrated. It is suggested that ablation formed gas-vapor bubbles can serve as templets for generation of hollow structures.

laser ablation

metal nanocompositions

ZrO2

RAMAN spectra

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