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  2. All Volumes and Issues
  3. Volume 14, Number 4, 2020
  4. Synthesis of Epoxyperoxides and Peroxide Derivatives of α-D-Galactopyranose Based Thereon

Synthesis of Epoxyperoxides and Peroxide Derivatives of α-D-Galactopyranose Based Thereon

JCCT.
2020;
Volume 14, Number 4
: pp. 439 - 447
https://doi.org/10.23939/chcht14.04.439
Authors:
  1. Roman Fleychuk
  2. Lidiya Vuytsyk
  3. Ananiy Kohut
  4. Orest Hevus
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University

New epoxide-containing peroxides have been synthesized via the interaction between epichlorohydrin and ditertiary ω-hydroxyalkyl peroxides. The effect of reaction conditions on both the yield and composition of the reaction products has been established. Through the reactions of either the synthesized epoxide-containing peroxides with 1,2;3,4-di-O-isopropylidene-α-D-galactopyranose or 6-O-glycidyl-1,2;3,4-di-O-isopropylidene-α-D-galactopyranose with the ω-hydroxyalkyl peroxides, new peroxide derivatives with ditertiary and primary-tertiary peroxide groups have been synthesized successfully. The decomposition of the developed substances has been studied by complex thermal analysis and the kinetic parameters of the thermolysis have been determined.

hydroxy-containing peroxides
epoxyalkyl peroxides
saccharides with peroxide groups
thermogravimetric analysis
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