Peculiarities of 13C NMR Spectra of Benzoylformic Acid and its Esters. 1. Benzoyl Fragment

Автори: 
Volodymyr Mizyuk and Volodymyr Shibanov

Peculiarities of 13C NMR spectra of benzoyl fragment of benzoylformic acid and its esters have been investigated and characteristic values of a chemical shift of all five types of fragment atom have been examined. Similar parameters of other benzoyl-containing compounds by general formula Bz–X (X = H, NR2, OR, SR, Cl, Br), as well as those of compounds Bz–C (L)(M)(N) have been compared. It has been shown that spectral peculiarities of a benzoylformates phenyl fragment are defined by the carbonyl, not by the carbalkoxyl group.

[1] Shibanov V., Mizjuk V. and Kobryn L.: Voprosy Khimii i Khim.Techn., 2005, 5, 51.
[2] Mizjuk V., Shibanov V., Kobrin L. et al.: Chem. & Chem. Techn., 2008, 2, 77. 
[3] Mizjuk V., Shibanov V., Kobrin L. et al.: Chem. & Chem. Techn., 2008, 2, 249.
[4] Mizjuk V., Shibanov V. and Marshalok I.: Zh. Org. Khim., 1994, 30, 601.
[5] Aldrich/ACD Library of FT NMR Spectra (Pro) Data Base Window.
[6] http:// www.aist.go.jp.
[7] Gordon A. and Ford P.: Sputnik Khimika. Moscow 1976.