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  4. Obtaining of Functional Surface Active Monomers Based on tert-Butylperoxy-6-hydroxyhexanoate

Obtaining of Functional Surface Active Monomers Based on tert-Butylperoxy-6-hydroxyhexanoate

JCCT.
2011;
Volume 5, Number 4
Authors: 

Mykola Borzenkov, Larysa Dolynska, Viktoriia Kochubei, Zoriana Nadashkevich and Orest Hevus

The interaction of -caprolactone with tert-butylhydroperoxide led to tert-butylperoxyhexanoate. Peroxymaleinate has been obtained by the reaction of tert-butylperoxyhexanoate with a maleic anhydride. Functional monomers have been synthesized by reactions of peroxymaleinate with propansultone and polyethylene glycol (PEG). The obtained compounds exhibit surface active properties, reducing a surface tension at the water-air interface.

e-caprolactone
peroxides
surface active monomers
surface tension.

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