RESEARCH ON THE STRUCTURE FORMATION PROCESSES IN THE SYSTEM «BLAST FURNANCE SLAG - WASTEPAPER SLUDGE ASH»

2024;
: 80-85
https://doi.org/10.23939/jtbp2024.01.080
Received: March 07, 2024
Revised: April 22, 2024
Accepted: May 02, 2024
1
Lviv Polytechnic National University, Department of Highways and Bridges
2
Lviv Polytechnic National University, Department of highways and bridges
3
Lviv Polytechnic National University, Department of highways and bridges
4
Lviv Polytechnic National University, Department of highways and bridges

Concrete production is one of the largest consumers of natural non-metallic materials. To mitigate the environmental impact associated with cement production The use of wastepaper sludge ash (WSA) from paper recycling is a new promising direction for saving fuel, energy, and natural resources in cement and concrete production, aimed at reducing the proportion of clinker in cement by replacing part of the cement with supplementary cementitious materials. This approach aligns with the priority principles of uniform and sustainable industry development aimed at creating environmentally friendly, low-energy-consuming technologies. This study is dedicated to investigating the properties of composite systems with different proportions of blast furnace granulated slag and wastepaper sludge ash. Test results show that samples with 70% WSA achieve the highest early strength (2.23 MPa flexural, 7.6 MPa compressive). Later, samples with a 70:30 BFS:TAW ratio exhibit the highest strength (38.3 MPa compressive, 4.6 MPa flexural) due to predominant hydro silicate hydration. The composite system forms CSH(B) hydro silicates and calcium hydro aluminate C4AH13, reacting with WSA gypsum to form calcium hydro sulpho aluminate C3A∙3CaSO4∙32H2O during initial hydration.

Di Fraia, S., & Uddin, M. R. (2022). Energy Recovery from Waste Paper and Deinking Sludge to Support the Demand of the Paper Industry: A Numerical Analysis. Sustainability, 14(8), 4669. DOI: 10.3390/su14084669.
https://doi.org/10.3390/su14084669
Lou, R., Wu, S., Lv, G., & Yang, Q. (2012). Energy and resource utilization of deinking sludge pyrolysis. Applied Energy, 90(1), 46-50. DOI: 10.1016/j.apenergy.2010.12.025.
https://doi.org/10.1016/j.apenergy.2010.12.025
Liu, M., Tan, S., Zhang, M., He, G., Chen, Z., Fu, Z., & Luan, C. (2020). Waste paper recycling decision system based on material flow analysis and life cycle assessment: A case study of waste paper recycling from China. Journal of Environmental Management, 255, 109859. DOI: 10.1016/j.jenvman.2019.109859.
https://doi.org/10.1016/j.jenvman.2019.109859
Monte, M. C., Fuente, E., Blanco, A., & Negro, C. (2009). Waste management from pulp and paper production in the European Union. Waste Management, 29(1), 293-308. https://doi.org/10.1016/j.wasman.2008.02.002
https://doi.org/10.1016/j.wasman.2008.02.002
Bajpai, P. (2015). Management of Pulp and Paper Mill Waste. Springer International Publishing, 193 p. http://dx.doi.org/10.1007/978-3-319-11788-1
https://doi.org/10.1007/978-3-319-11788-1
Frias, M., Garcia, R., Vigil, R., & Ferreiro, S. (2001). Calcinations of art paper sludge waste for the use as a supplementary cementing material. Applied Clay Science, 42(1-2), 189-193. http://dx.doi.org/10.1016/j.clay.2008.01.013
https://doi.org/10.1016/j.clay.2008.01.013
Bikila Meko, Joshua Ighalo, Pengcheng Jiao (Reviewing editor). Utilization of waste paper ash as supplementary cementitious material in C-25 concrete: Evaluation of fresh and hardened properties. Cogent Engineering, 2021, 8:1. DOI: 10.1080/23311916.2021.1938366.
https://doi.org/10.1080/23311916.2021.1938366
Solahuddin, B. A., & Yahaya, F. M. A Review Paper on The Effect of Waste Paper on Mechanical Properties of Concrete. In IOP Conference Series: Materials Science and Engineering, 2021, Vol. 1092, No. 1, p. 012067. IOP Publishing. http://dx.doi.org/10.1088/1757-899X/1092/1/012067.
https://doi.org/10.1088/1757-899X/1092/1/012067
Ahmad, S., Malik, M. I., Wani, M. B., & Ahmad, R. Study of concrete involving the use of waste paper sludge ash as partial replacement of cement. IOSR Journal of Engineering, 2013, 3(11), 06-15. http://dx.doi.org/10.9790/3021-031130615.
https://doi.org/10.9790/3021-031130615
Sobol, K., Solodkyy, S., Petrovska, N., Belov, S., Hunyak, O., & Hidei, V. (2020). Chemical Composition and Hydraulic Properties of Incinerated Wastepaper Sludge. Chemistry & Chemical Technology, 14, 538-544. https://doi.org/10.23939/chcht14.04.538
https://doi.org/10.23939/chcht14.04.538
Hunyak, O., Hidei, V., Sobol, K., & Petrovska, N. (2022). Valorization of Wastepaper Sludge Ash as Supplementary Cementitious Material in Concrete. Proceedings of EcoComfort, 94-100. DOI:10.1007/978-3-031-14141-6_10
https://doi.org/10.1007/978-3-031-14141-6_10
Sobol, K. S., Markiv, T. Y., Petrovska, N. I., & Hidei, V. V. (2019). Analysis of the effectiveness of using finely ground blast furnace granulated slag in concrete. Visnyk Natsionalnoho universytetu "Lvivska politekhnika". Seriia: Teoriia i praktyka budivnytstva, (912), 169-174. https://science.lpnu.ua/uk/node/19687
Ishimoto, H., Origuchi, T., Yasuda, M. (2000). Use of paper mill sludge as a new material. J Mater Civ Eng, 12(1), 310-313. http://dx.doi.org/10.1061/(ASCE)0899-1561(2000)12:4(310)
https://doi.org/10.1061/(ASCE)0899-1561(2000)12:4(310)
Doudart de la Grée, G.C.H., Yu, Q.L., Brouwers, H.J.H. (2018). Improvement and evaluation of paper mill sludge ash in environmentally lightweight cement composites. J Mater Civ Eng. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002186
https://doi.org/10.1061/(ASCE)MT.1943-5533.0002186
Fava, G., Ruello, M.L., Corinaldesi, V. (2011). Paper mill sludge ash as an additional cementitious material. J Mater Civ Eng, 23, 772-776. http://dx.doi.org/10.1061/(ASCE)MT.1943-5533.0000218
https://doi.org/10.1061/(ASCE)MT.1943-5533.0000218
Mozafari, E., O'Farrell, M., Kinuthia, J.M., Wild, S. (2006). Enhancement of strength development of paper mill sludge ash by wet milling. Cem Concr Compos, 28, 144-152. http://dx.doi.org/10.1016/j.cemconcomp.2005.10.007
https://doi.org/10.1016/j.cemconcomp.2005.10.007
Mozafari, E., Kinuthia, J.M., Wild, J., Bai, S. (2009). Investigation into the strength development of paper mill sludge ash blended with ground granulated blast furnace slag. Cem Concr Res, 39, 942-949. http://dx.doi.org/10.1016/j.cemconres.2009.07.001
https://doi.org/10.1016/j.cemconres.2009.07.001
Frías, M., Vegas, I., de la Villa, R. V., & Giménez, R. G. (2011). Recycling of paper mill waste ash in cements: characterization and behavior of new eco-efficient matrices. Integr Waste Manage, 2, 11301. http://dx.doi.org/10.5772/20850.
https://doi.org/10.5772/20850
Frías, M., Rodríguez, O., & De Rojas, M. S. (2015). Paper mill sludge, an environmentally sound alternative for MK-based cementitious materials: A review. Construction and Building Materials, 74, 37-48. http://dx.doi.org/10.1016/j.conbuildmat.2014.10.007
https://doi.org/10.1016/j.conbuildmat.2014.10.007
Banfill, P., & Frías, M. (2007). Rheology and conduction calorimetry of cement modified with calcined paper mill sludge. Cement and concrete research, 37(2), 184-190. https://doi.org/10.1016/j.cemconres.2006.11.013
https://doi.org/10.1016/j.cemconres.2006.11.013