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INFLUENCE OF TUNGSTEN COMPOUNDS ON REACTION OF 1-OCTENE EPOXIDATION BY TERT-BUTYL HYDROPEROXIDE AND HYDROPEROXIDE DECOMPOSITION

Catalytic ability of tungsten compounds in the reaction of hydroperoxide epoxidation of 1- octene and tert-butyl hydroperoxide decomposition was investigated. It is shown that the nature of ligand has significant effect on the catalytic activity of tungsten compounds in these reactions. It is established that boride and silicide of tungsten are the best choice for epoxidation reaction, whereas tungsten carbide exhibits poor activity. Tungsten boride is also the most active in the hydroxide decomposition reaction.

Theoretical analysis and experimental study of H2S dissociation processes in ultrahigh-frequency plasmotron

Theoretical analysis of aerodynamic conditions in a plasma chemical reactor with tangential gas supply is carried out. It is shown that due to the creation of a swirling flow in the reactor there is a pressure gradient, due to this along the vertical axis there is a vacuum zone, which contributes to the occurrence of plasma discharge.

INTRODUCTION OF THE INFORMATION AND REFERENCE SYSTEM "UNIBELL" IN THE EDUCATIONAL ENVIRONMENT INSTITUTION OF HIGHER EDUCATION

Scientific work is aimed to identifying problem areas during distance educational process and to development of services that could help of solving them. Empirical methods and methods of real-life observation were used to collect the initial data for study. Processing of the obtained data is performed on the basis of using analytical methods and methods of expert evaluations.

Degradation Oxirane Ring Kinetics of Epoxidized Palm Kernel Oil-Based Crude Oleic Acid

The epoxidation of oleic acid was carried out by using in situ generated performic acid (HCOOOH) to produce epoxidized oleic acid. Performic acid was formed by mixing formic acid (as oxygen carrier) and hydrogen peroxide (as oxygen donor). The epoxide ring is very reactive, especially in the presence of acidic condition making the epoxide a suitable intermediate for synthesis of other chemicals. The most likely side reaction that occurred in the in situ epoxidation is the reaction of oxirane ring with formic acid, which led to formation of diol and a-glycol as side products.