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  3. Volume 14, Number 2, 2020
  4. Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes

Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes

JCCT.
2020;
Volume 14, Number 2
: pp. 135 - 138
https://doi.org/10.23939/chcht14.02.135
Authors:
  1. Tetiana Bilous
  2. Alena Tulskaya
  3. Issam Chahine
  4. Volodymyr Bairachnyi
1
National Technical University “Kharkiv Polytechnic Institute”
2
National Technical University “Kharkiv Polytechnic Institute”
3
National Technical University “Kharkiv Polytechnic Institute”
4
National Technical University “Kharkiv Polytechnic Institute”

The kinetics of anodic processes on Pt/PtO and PbO2 anodes has been studied in water solutions of acetic acid. The addition of sulfuric acid has a catalytic effect in the electrochemical synthesis of peroxyacetic acid. The choice of promoters of peroxide-particles formation has been proved. I–, Cl– (current efficiency is 1.2–1.5 %) particles have been defined as the most effective for platinum anode and I–, F– (current efficiency is 0.50–0.55 %) have been defined as the most effective for lead-dioxide anode.

peroxyacetic acid
acetic acid
platinum anode
lead-dioxide anode
promoter
peroxide particles
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