extraction

Adequacy of mathematical model of the extraction process of solid bodies of cellular structure (plant material) was proved with taking into account its anatomical structure, namely the presence of cellular and intercellular environment. Experimental verification of the mechanism of extracting of intracellular substance during extraction process flow was made. An order of diffusion coefficients through cellular membrane – Dc and in intercellular environment Dт was confirmed.

A mathematical model of mass transfer from lamina (plant leaf) into the extractant is constructed considering its anatomical organization in particular the existence of cellular and intercellular space. Its solution allows to predict kinetics of the extraction process of the whole leaves at its implementation in practice.

Using maximum extraction of carbon-containing components the content of amorphous silicon dioxide was increased in the rice husk solid residue. In accordance with the hypothesis about the mechanism of extracting carbon-containing components from rice husk by liquid extractants, proper extractants were selected. The effect of main technological factors including process temperature, time and concentration of the extractants was determined.

The creation of Cu2+ ions chelate complex with 1-(5-benzylthiazol-2-yl)azonaphthalen-2-ol has been investigated using spectrophotometric methods. The optimal conditions for the complexation reaction and for extraction into the organic phase were found. The extraction-photometric method of copper microquantities determination was developed.

The process of cyanobacteria complex treatment via obtaining of inedible fat, suitable for the production of biodiesel and biogas has been investigated. The prospective application of hydrodynamic cavitation to increase the efficiency of inedible fat extraction and biogas synthesis is shown. A comprehensive strategy for the cyanobacteria use in the energy and agricultural technologies is suggested.

Solvent-free microwave extraction (SFME) is proposed as a method for “green” extraction of edible essential oils extensively used in the fragrance, flavour, and pharmaceutical industries and also in aromatherapy. It is a combination of microwave heating and dry distillation, performed at atmospheric pressure without adding any solvent or water. Isolation and concentration of volatile compounds are performed by a single stage. Basil (Ocimum basilicum L.) was extracted with SFME at atmospheric pressure and 373 K for 30 min.

Developing new, eco-friendly solvents which would meet technological and economic demands is perhaps the most popular aspects of Green Chemistry. Natural deep eutectic solvents (NADES) fully meet green chemistry principles. These solvents offer many advantages including biodegradability, low toxicity, sustainability, low costs and simple preparation. This paper provides an overview of knowledge regarding NADES with special emphasis on extraction applications and further perspectives as truly sustainable solvents.